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- W3127945906 endingPage "125261" @default.
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- W3127945906 abstract "Coprecipitation with calcium carbonate (CaCO3) could decrease the bioavailability of arsenic (As). However, in a phosphate-rich environment, some CaCO3 will be converted to hydroxylapatite (HAP). Currently, the behavior of carbonate-bound As during conversion is unclear. Therefore, we prepared bio-induced CaCO3 in an As solution and converted it to HAP. The results showed that a high concentration of arsenate promoted vaterite precipitation and the conversion of CaCO3 to HAP. The dissolution data verified the low solubility of As in HAP, though its As-bearing CaCO3 precursor released up to 88.19% As during the conversion. Furthermore, HPLC-ICP-MS data showed partial oxidation of arsenite to arsenate, suggesting that CaCO3 and HAP's structure favored the incorporation of arsenate. Our results demonstrated that the stability of heavy metal-bearing CaCO3 should be considered, and the role of HAP in the immobilization of heavy metals such as As should not be overestimated." @default.
- W3127945906 created "2021-02-15" @default.
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- W3127945906 date "2021-06-01" @default.
- W3127945906 modified "2023-10-14" @default.
- W3127945906 title "Immobilization and migration of arsenic during the conversion of microbially induced calcium carbonate to hydroxylapatite" @default.
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- W3127945906 doi "https://doi.org/10.1016/j.jhazmat.2021.125261" @default.
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