Matches in SemOpenAlex for { <https://semopenalex.org/work/W3128204554> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W3128204554 endingPage "115075" @default.
- W3128204554 startingPage "115075" @default.
- W3128204554 abstract "Two novel dicarbonyl-semiquinonato rhodium complexes were synthesized and studied. Complexes are analogues of (CO)2Rh(3,6-DBSQ) (3,6-DBSQ-3,6-di-tert-butyl-o-benzosemiquinone) which thread-like crystals can bend reversibly under light or heat activation (G.A. Abakumov, V.I. Nevodchikov, Dokl. Acad. Nauk SSSR 1982, 266, 1407–1410). Complexes differ from (CO)2Rh(3,6-DBSQ) by substituents in 3,6-positions of quinonato ring (cyclohexyl (1) and isopropyl (2) instead of tert-butyl). Single crystal structural study indicates that both complexes are the derivatives of Rh(I) with o-semiquinonato anion-radical. Molecules form pairs due the short contacts in contrast to (CO)2Rh(3,6-DBSQ) and other similar compounds which form the endless alternated chains with direct Rh-Rh bond. At that, complex 1 molecules form isolated pairs, whereas molecules of 2 can be united in the chain. Both compounds 1 and 2 have the array of intensive bands in IR spectrum in the region 1350 cm−1 which is closer to bond stretch vibrations of C–O ordinary bond but not sesquilateral. EPR of solutions of complexes indicates presence of monomeric complex molecules where the single unpaired electron is localized in o-semiquinonato ligand. The drop of EPR signal intensity with cooling of solutions of 1 and 2 evidence that the association process takes place." @default.
- W3128204554 created "2021-02-15" @default.
- W3128204554 creator A5041254666 @default.
- W3128204554 creator A5052785880 @default.
- W3128204554 creator A5068633103 @default.
- W3128204554 creator A5069352132 @default.
- W3128204554 creator A5078657891 @default.
- W3128204554 creator A5088869399 @default.
- W3128204554 date "2021-04-01" @default.
- W3128204554 modified "2023-09-26" @default.
- W3128204554 title "Di-carbonyl-o-semiquinonato rhodium complexes" @default.
- W3128204554 cites W1974121289 @default.
- W3128204554 cites W1980378358 @default.
- W3128204554 cites W2000591257 @default.
- W3128204554 cites W2002576040 @default.
- W3128204554 cites W2016231232 @default.
- W3128204554 cites W2027009300 @default.
- W3128204554 cites W2132454074 @default.
- W3128204554 cites W2170495055 @default.
- W3128204554 doi "https://doi.org/10.1016/j.poly.2021.115075" @default.
- W3128204554 hasPublicationYear "2021" @default.
- W3128204554 type Work @default.
- W3128204554 sameAs 3128204554 @default.
- W3128204554 citedByCount "1" @default.
- W3128204554 countsByYear W31282045542022 @default.
- W3128204554 crossrefType "journal-article" @default.
- W3128204554 hasAuthorship W3128204554A5041254666 @default.
- W3128204554 hasAuthorship W3128204554A5052785880 @default.
- W3128204554 hasAuthorship W3128204554A5068633103 @default.
- W3128204554 hasAuthorship W3128204554A5069352132 @default.
- W3128204554 hasAuthorship W3128204554A5078657891 @default.
- W3128204554 hasAuthorship W3128204554A5088869399 @default.
- W3128204554 hasConcept C104264131 @default.
- W3128204554 hasConcept C115624301 @default.
- W3128204554 hasConcept C116569031 @default.
- W3128204554 hasConcept C121332964 @default.
- W3128204554 hasConcept C155647269 @default.
- W3128204554 hasConcept C161790260 @default.
- W3128204554 hasConcept C166940927 @default.
- W3128204554 hasConcept C170493617 @default.
- W3128204554 hasConcept C178790620 @default.
- W3128204554 hasConcept C185592680 @default.
- W3128204554 hasConcept C186927785 @default.
- W3128204554 hasConcept C187961010 @default.
- W3128204554 hasConcept C32909587 @default.
- W3128204554 hasConcept C46141821 @default.
- W3128204554 hasConcept C521398313 @default.
- W3128204554 hasConcept C521977710 @default.
- W3128204554 hasConcept C55493867 @default.
- W3128204554 hasConcept C71240020 @default.
- W3128204554 hasConcept C8010536 @default.
- W3128204554 hasConceptScore W3128204554C104264131 @default.
- W3128204554 hasConceptScore W3128204554C115624301 @default.
- W3128204554 hasConceptScore W3128204554C116569031 @default.
- W3128204554 hasConceptScore W3128204554C121332964 @default.
- W3128204554 hasConceptScore W3128204554C155647269 @default.
- W3128204554 hasConceptScore W3128204554C161790260 @default.
- W3128204554 hasConceptScore W3128204554C166940927 @default.
- W3128204554 hasConceptScore W3128204554C170493617 @default.
- W3128204554 hasConceptScore W3128204554C178790620 @default.
- W3128204554 hasConceptScore W3128204554C185592680 @default.
- W3128204554 hasConceptScore W3128204554C186927785 @default.
- W3128204554 hasConceptScore W3128204554C187961010 @default.
- W3128204554 hasConceptScore W3128204554C32909587 @default.
- W3128204554 hasConceptScore W3128204554C46141821 @default.
- W3128204554 hasConceptScore W3128204554C521398313 @default.
- W3128204554 hasConceptScore W3128204554C521977710 @default.
- W3128204554 hasConceptScore W3128204554C55493867 @default.
- W3128204554 hasConceptScore W3128204554C71240020 @default.
- W3128204554 hasConceptScore W3128204554C8010536 @default.
- W3128204554 hasFunder F4320324099 @default.
- W3128204554 hasLocation W31282045541 @default.
- W3128204554 hasOpenAccess W3128204554 @default.
- W3128204554 hasPrimaryLocation W31282045541 @default.
- W3128204554 hasRelatedWork W2018508933 @default.
- W3128204554 hasRelatedWork W2045237681 @default.
- W3128204554 hasRelatedWork W2053945339 @default.
- W3128204554 hasRelatedWork W2088939160 @default.
- W3128204554 hasRelatedWork W2138891713 @default.
- W3128204554 hasRelatedWork W2332841977 @default.
- W3128204554 hasRelatedWork W2386046626 @default.
- W3128204554 hasRelatedWork W2504256629 @default.
- W3128204554 hasRelatedWork W2739936718 @default.
- W3128204554 hasRelatedWork W2767205953 @default.
- W3128204554 hasVolume "198" @default.
- W3128204554 isParatext "false" @default.
- W3128204554 isRetracted "false" @default.
- W3128204554 magId "3128204554" @default.
- W3128204554 workType "article" @default.