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- W3128263299 abstract "A new polyoxoniobate constructed by four {Nb27} building blocks, K11[Cu(en)2(H2O)2]2[H29{Cu(en)2}4{Cu0.5(en)2}4{Cu(en)2(H2O)}4(OH)4(Nb27O75)4]·103H2O (en = ethanediamine), has been synthesized and characterized. Four {Nb27} inorganic blocks are linked by metal-organic components [Cu(en)2]2+, forming a tetrameric organic–inorganic hybrid. The structure is characterized by IR spectroscopy, XRD, UV–vis, EPR, single crystal X-ray diffraction, thermal gravimetric analysis and elemental analysis. Furthermore, the solution behavior was investigated indicating the integrity of {Nb27} building block, which shows the possibility that it might be an excellent precursor for functionalization." @default.
- W3128263299 created "2021-02-15" @default.
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- W3128263299 date "2021-02-10" @default.
- W3128263299 modified "2023-10-17" @default.
- W3128263299 title "A new organic–inorganic hybrid polyoxoniobate based on {Nb<sub>27</sub>}" @default.
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- W3128263299 doi "https://doi.org/10.1080/00958972.2021.1882675" @default.
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