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• W3128324333 abstract "A general procedure of 1,2-dibromination of vicinal sp3 C–H bonds of arylethanes using N-bromosuccinimide as the bromide reagent without an external initiator has been established. The modulation of the strength of the intermolecular noncovalent interactions between the solvent and arylethane ethanes, quantitatively evaluated via quantum chemical calculations, allows us to circumvent the fact that arylethane ethane cannot be dibrominated through traditional methods. The mechanism was explored by both experiments and quantum chemical calculations, revealing a radical chain with HAA process." @default.
• W3128324333 created "2021-02-15" @default.
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• W3128324333 date "2021-02-10" @default.
• W3128324333 modified "2023-09-30" @default.
• W3128324333 title "A General Method for the Dibromination of Vicinal sp³ C–H Bonds Exploiting Weak Solvent–Substrate Noncovalent Interactions" @default.
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• W3128324333 doi "https://doi.org/10.1021/acs.orglett.0c04235" @default.
• W3128324333 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33566622" @default.
• W3128324333 hasPublicationYear "2021" @default.
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