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• W3128349087 endingPage "267" @default.
• W3128349087 startingPage "259" @default.
• W3128349087 abstract "The silatrane hydride compound, [N(CH 2 CH 2 O) 3 ]SiH, reacts with CO 2 in the presence of the [tris(2-pyridylthio)methyl]zinc hydride complex, [Tptm]ZnH, to afford the silyl formate and methoxide derivatives, [N(CH 2 CH 2 O) 3 ]SiO 2 CH and [N(CH 2 CH 2 O) 3 ]SiOCH 3 . The molecular structure of [N(CH 2 CH 2 O) 3 ]SiO 2 CH has been determined by X-ray diffraction, thereby demonstrating that the formate ligand adopts a distal conformation in which the uncoordinated oxygen atom resides with a trans-like disposition relative to silicon. Density functional theory calculations indicate that the atrane motif of [N(CH 2 CH 2 O) 3 ]SiO 2 CH is flexible, such that the energy of the molecule changes relatively little as the Si···N distance varies over the range 2.0–3.0 Å." @default.
• W3128349087 created "2021-02-15" @default.
• W3128349087 creator A5042820895 @default.
• W3128349087 creator A5072093741 @default.
• W3128349087 creator A5075865104 @default.
• W3128349087 creator A5076398404 @default.
• W3128349087 date "2021-02-01" @default.
• W3128349087 modified "2023-09-26" @default.
• W3128349087 title "Hydrosilyation of CO₂ using a silatrane hydride: structural characterization of a silyl formate compound" @default.
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