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- W3128905413 abstract "Abstract The non‐oxidative dehydrogenation of propane to propylene plays an important role in the light‐olefin chemical industry. However, the conversion and selectivity remain a fundamental challenge at low temperatures. Here we create and engineer high‐density Lewis acid sites at well‐defined surfaces in porous single‐crystalline Mo 2 N and MoN monoliths to enhance the non‐oxidative dehydrogenation of propane to propylene. The top‐layer Mo ions with unsaturated Mo‐N 1/6 and Mo‐N 1/3 coordination structures provide high‐density Lewis acid sites at the surface, leading to the effective activation of C−H bonds without the overcracking of C−C bonds during the non‐oxidative dehydrogenation of propane. We demonstrate a propane conversion of ≈11 % and a propylene selectivity of ≈95 % with porous single‐crystalline Mo 2 N and MoN monoliths at 500 °C." @default.
- W3128905413 created "2021-02-15" @default.
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- W3128905413 date "2021-03-10" @default.
- W3128905413 modified "2023-09-30" @default.
- W3128905413 title "High‐Density Lewis Acid Sites in Porous Single‐Crystalline Monoliths to Enhance Propane Dehydrogenation at Reduced Temperatures" @default.
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- W3128905413 doi "https://doi.org/10.1002/anie.202100244" @default.
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