FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3128963900> ?p ?o ?g. }

• W3128963900 endingPage "786" @default.
• W3128963900 startingPage "776" @default.
• W3128963900 abstract "ConspectusA knowledge of colloidal semiconductor magic-size clusters (MSCs) is essential for understanding how fundamental properties evolve during transformations from individual molecules to semiconductor quantum dots (QDs). Compared to QDs, MSCs display much narrower optical absorption bands; the higher cluster stability gives rise to a narrower size distribution. During the production of binary QDs such as II–VI metal (M) chalcogenide (E) ones, binary ME MSCs observed were interpreted as side products and/or the nuclei of QDs. Prior to the current development of our two-step approach followed by our two-pathway model, it had been extremely challenging to synthesize MSCs as a unique product without the nucleation and growth of QDs. With the two-step approach, we have demonstrated that MSCs can be readily engineered as a sole product at room temperature from a prenucleation stage sample, also called an induction period (IP) sample. It is important that we were able to discover that the evolution of the MSCs follows first-order reaction kinetics behavior. Accordingly, we proposed that a new type of compound, termed as “precursor compounds” (PCs) of MSCs, was produced in an IP sample. Such PCs are optically transparent at the absorption peak positions of their MSC counterparts as well as to longer wavelengths. It is thought that quasi isomerization of a single PC results in the development of one MSC.In this Account, we provide an overview of our latest advances regarding the transformations among binary CdE MSCs as well as from binary CdTe to ternary CdTeSe MSCs. Optical absorption spectroscopy has been employed to study these transformations, all of which display well-defined isosbestic points. We have proposed that these MSC to MSC transformations occur via their corresponding PCs, also called immediate PCs. It is reasonable that the as-synthesized PC (in an IP sample) and the immediate PC (in an incubated and/or diluted sample) probably have different configurations. A transformation between two PCs may involve an intermolecular reaction, with either first-order reaction kinetics or a more complicated time profile. A transformation between one immediate PC and its counterpart MSC may contain an intramolecular reaction. The present Account, which addresses the PC-enabled MSC transformations with isosbestic points probed by optical absorption spectroscopy, calls for more experimental and theoretical attention to understand these magic species and their transformation processes more precisely." @default.
• W3128963900 created "2021-02-15" @default.
• W3128963900 creator A5000865193 @default.
• W3128963900 creator A5041237261 @default.
• W3128963900 creator A5041494906 @default.
• W3128963900 creator A5041773385 @default.
• W3128963900 creator A5055113175 @default.
• W3128963900 creator A5066077301 @default.
• W3128963900 date "2021-02-03" @default.
• W3128963900 modified "2023-10-17" @default.
• W3128963900 title "Transformations Among Colloidal Semiconductor Magic-Size Clusters" @default.
• W3128963900 cites W1967392716 @default.
• W3128963900 cites W1997466842 @default.
• W3128963900 cites W2016225667 @default.
• W3128963900 cites W2025296054 @default.
• W3128963900 cites W2025306977 @default.
• W3128963900 cites W2033727896 @default.
• W3128963900 cites W2036558067 @default.
• W3128963900 cites W2037431566 @default.
• W3128963900 cites W2042777242 @default.
• W3128963900 cites W2049306737 @default.
• W3128963900 cites W2061889705 @default.
• W3128963900 cites W2062211329 @default.
• W3128963900 cites W2086821232 @default.
• W3128963900 cites W2133200034 @default.
• W3128963900 cites W2155947729 @default.
• W3128963900 cites W2314946862 @default.
• W3128963900 cites W2320594594 @default.
• W3128963900 cites W2325793081 @default.
• W3128963900 cites W2326188644 @default.
• W3128963900 cites W2326252434 @default.
• W3128963900 cites W2327250759 @default.
• W3128963900 cites W2527968534 @default.
• W3128963900 cites W2591297204 @default.
• W3128963900 cites W2613316150 @default.
• W3128963900 cites W2622566947 @default.
• W3128963900 cites W2660958675 @default.
• W3128963900 cites W2785470913 @default.
• W3128963900 cites W2788190706 @default.
• W3128963900 cites W2804579565 @default.
• W3128963900 cites W2808795611 @default.
• W3128963900 cites W2809340155 @default.
• W3128963900 cites W2889063679 @default.
• W3128963900 cites W2897156113 @default.
• W3128963900 cites W2898114881 @default.
• W3128963900 cites W2936304291 @default.
• W3128963900 cites W2940405129 @default.
• W3128963900 cites W2945268628 @default.
• W3128963900 cites W2946385719 @default.
• W3128963900 cites W2963665802 @default.
• W3128963900 cites W2980310406 @default.
• W3128963900 cites W2996256122 @default.
• W3128963900 cites W3003917878 @default.
• W3128963900 cites W3009398246 @default.
• W3128963900 cites W3021748822 @default.
• W3128963900 cites W3036170959 @default.
• W3128963900 cites W3036523836 @default.
• W3128963900 cites W3048850512 @default.
• W3128963900 cites W3081082265 @default.
• W3128963900 cites W3099201542 @default.
• W3128963900 doi "https://doi.org/10.1021/acs.accounts.0c00702" @default.
• W3128963900 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33533599" @default.
• W3128963900 hasPublicationYear "2021" @default.
• W3128963900 type Work @default.
• W3128963900 sameAs 3128963900 @default.
• W3128963900 citedByCount "30" @default.
• W3128963900 countsByYear W31289639002021 @default.
• W3128963900 countsByYear W31289639002022 @default.
• W3128963900 countsByYear W31289639002023 @default.
• W3128963900 crossrefType "journal-article" @default.
• W3128963900 hasAuthorship W3128963900A5000865193 @default.
• W3128963900 hasAuthorship W3128963900A5041237261 @default.
• W3128963900 hasAuthorship W3128963900A5041494906 @default.
• W3128963900 hasAuthorship W3128963900A5041773385 @default.
• W3128963900 hasAuthorship W3128963900A5055113175 @default.
• W3128963900 hasAuthorship W3128963900A5066077301 @default.
• W3128963900 hasConcept C108225325 @default.
• W3128963900 hasConcept C124657808 @default.
• W3128963900 hasConcept C125287762 @default.
• W3128963900 hasConcept C147789679 @default.
• W3128963900 hasConcept C159467904 @default.
• W3128963900 hasConcept C159985019 @default.
• W3128963900 hasConcept C171250308 @default.
• W3128963900 hasConcept C178790620 @default.
• W3128963900 hasConcept C185592680 @default.
• W3128963900 hasConcept C192562407 @default.
• W3128963900 hasConcept C199360897 @default.
• W3128963900 hasConcept C2778177714 @default.
• W3128963900 hasConcept C41008148 @default.
• W3128963900 hasConcept C49040817 @default.
• W3128963900 hasConcept C59789625 @default.
• W3128963900 hasConcept C61048295 @default.
• W3128963900 hasConcept C64452783 @default.
• W3128963900 hasConceptScore W3128963900C108225325 @default.
• W3128963900 hasConceptScore W3128963900C124657808 @default.
• W3128963900 hasConceptScore W3128963900C125287762 @default.
• W3128963900 hasConceptScore W3128963900C147789679 @default.
• W3128963900 hasConceptScore W3128963900C159467904 @default.

• next