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- W312912686 abstract "The equilibria of reactions of extraction of trivalent ions of the lanthanides and actinides by trialkylammonium salts of various structures were calculated by the methods of statistical physics. A comparison of the calculated and experimental data showed that the differences in sensitivity of the distribution coefficients of the individual f-elements to changes in the configuration of the hydrocarbon portion of the extraction reagent are determined by differences in the structure of the inner coordination sphere of the metal. Therefore, the influence of steric factors on the selectivity of extraction is most distinctly manifested in the region of a change in the nature of the coordination of the ligands in the series of f-elements." @default.
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- W312912686 date "1975-01-01" @default.
- W312912686 modified "2023-09-23" @default.
- W312912686 title "Influence of the structure of extraction reagents on the selectivity of the extraction of actinide and lanthanide elements. [Trialkylammonium salts]" @default.
- W312912686 hasPublicationYear "1975" @default.
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