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- W3129166012 abstract "Considering the importance of the chiral allylic amine structural motif and the rarity of synthetic methods toward their construction, herein, we report a CpXRh(III)-catalyzed enantioselective intermolecular carboamination of 1,3-dienes via N-phenoxy amides-derived intermolecular aryl C–H activation and intramolecular amide transfer. The methodology enables the direct synthesis of a variety of chiral allylic amines with the embedment of phenol functionalities and proceeds under mild conditions with sequential formation of a completely regioselective C–C bond and a highly enantioselective C–N bond. Integrated experimental and computational mechanistic studies reveal an unusual Rh(III)–Rh(I)–Rh(III) catalytic pathway, in which an alkene insertion/π-allylation/intramolecular nucleophilic substitution cascade was involved for this transformation. Besides, synthetic application in the derivation of natural products and the late-stage assembly of bioactive complexes has also been demonstrated, which further strengthens the synthetic utility of this approach." @default.
- W3129166012 created "2021-02-15" @default.
- W3129166012 creator A5035680195 @default.
- W3129166012 creator A5038199259 @default.
- W3129166012 creator A5038259858 @default.
- W3129166012 creator A5038397278 @default.
- W3129166012 creator A5042141831 @default.
- W3129166012 creator A5070937100 @default.
- W3129166012 creator A5089356883 @default.
- W3129166012 date "2021-02-05" @default.
- W3129166012 modified "2023-10-14" @default.
- W3129166012 title "Chiral Allylic Amine Synthesis Enabled by the Enantioselective Cp<sup>X</sup>Rh(III)-Catalyzed Carboaminations of 1,3-Dienes" @default.
- W3129166012 cites W1972456842 @default.
- W3129166012 cites W1973018553 @default.
- W3129166012 cites W1976517267 @default.
- W3129166012 cites W1976867032 @default.
- W3129166012 cites W1987511097 @default.
- W3129166012 cites W1987587964 @default.
- W3129166012 cites W1994708284 @default.
- W3129166012 cites W2006352949 @default.
- W3129166012 cites W2006573539 @default.
- W3129166012 cites W2009012040 @default.
- W3129166012 cites W2011696949 @default.
- W3129166012 cites W2012314528 @default.
- W3129166012 cites W2013790981 @default.
- W3129166012 cites W2019237825 @default.
- W3129166012 cites W2021191303 @default.
- W3129166012 cites W2026788063 @default.
- W3129166012 cites W2029936213 @default.
- W3129166012 cites W2036758375 @default.
- W3129166012 cites W2041843816 @default.
- W3129166012 cites W2048705687 @default.
- W3129166012 cites W2049095005 @default.
- W3129166012 cites W2065578557 @default.
- W3129166012 cites W2071529772 @default.
- W3129166012 cites W2076859547 @default.
- W3129166012 cites W2087156643 @default.
- W3129166012 cites W2093229567 @default.
- W3129166012 cites W2103380929 @default.
- W3129166012 cites W2104510853 @default.
- W3129166012 cites W2106297416 @default.
- W3129166012 cites W2108579306 @default.
- W3129166012 cites W2113278931 @default.
- W3129166012 cites W2121041004 @default.
- W3129166012 cites W2121265473 @default.
- W3129166012 cites W2132923291 @default.
- W3129166012 cites W2139491375 @default.
- W3129166012 cites W2139945985 @default.
- W3129166012 cites W2153701075 @default.
- W3129166012 cites W2162047307 @default.
- W3129166012 cites W2166466785 @default.
- W3129166012 cites W2171576196 @default.
- W3129166012 cites W2278561760 @default.
- W3129166012 cites W2279524934 @default.
- W3129166012 cites W2312654583 @default.
- W3129166012 cites W2314717072 @default.
- W3129166012 cites W2317771072 @default.
- W3129166012 cites W2318193487 @default.
- W3129166012 cites W2334705630 @default.
- W3129166012 cites W2340442100 @default.
- W3129166012 cites W2529657426 @default.
- W3129166012 cites W2543157161 @default.
- W3129166012 cites W2564858020 @default.
- W3129166012 cites W2582614442 @default.
- W3129166012 cites W2589065087 @default.
- W3129166012 cites W2606788402 @default.
- W3129166012 cites W2744703866 @default.
- W3129166012 cites W2756202433 @default.
- W3129166012 cites W2781036133 @default.
- W3129166012 cites W2786926195 @default.
- W3129166012 cites W2791304971 @default.
- W3129166012 cites W2792686715 @default.
- W3129166012 cites W2796071904 @default.
- W3129166012 cites W2796187894 @default.
- W3129166012 cites W2807717507 @default.
- W3129166012 cites W2810545483 @default.
- W3129166012 cites W2889680708 @default.
- W3129166012 cites W2896276276 @default.
- W3129166012 cites W2899161518 @default.
- W3129166012 cites W2901931000 @default.
- W3129166012 cites W2907960580 @default.
- W3129166012 cites W2908596562 @default.
- W3129166012 cites W2911325032 @default.
- W3129166012 cites W2924013887 @default.
- W3129166012 cites W2936828926 @default.
- W3129166012 cites W2943343593 @default.
- W3129166012 cites W2948692488 @default.
- W3129166012 cites W2955707848 @default.
- W3129166012 cites W2958977950 @default.
- W3129166012 cites W2962337637 @default.
- W3129166012 cites W2965199269 @default.
- W3129166012 cites W2967011448 @default.
- W3129166012 cites W2969825324 @default.
- W3129166012 cites W2976366399 @default.
- W3129166012 cites W2977209774 @default.
- W3129166012 cites W2993096614 @default.
- W3129166012 cites W3003192628 @default.
- W3129166012 cites W3012665214 @default.