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- W3129207375 abstract "The production of cyclic carbonates from CO2 cycloaddition to epoxides, using the C-scorpionate iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz = 1H-pyrazol-1-yl) as a catalyst, is achieved in excellent yields (up to 98%) in a tailor-made ionic liquid (IL) medium under mild conditions (80 °C; 1–8 bar). A favorable synergistic catalytic effect was found in the [FeCl2{κ3-HC(pz)3}]/IL system. Notably, in addition to exhibiting remarkable activity, the catalyst is stable during ten consecutive cycles, the first decrease (11%) on the cyclic carbonate yield being observed during the 11th cycle. The use of C-scorpionate complexes in ionic liquids to afford cyclic carbonates is presented herein for the first time." @default.
- W3129207375 created "2021-03-01" @default.
- W3129207375 creator A5010912848 @default.
- W3129207375 creator A5073346147 @default.
- W3129207375 date "2021-02-19" @default.
- W3129207375 modified "2023-09-26" @default.
- W3129207375 title "Efficient and Reusable Iron Catalyst to Convert CO2 into Valuable Cyclic Carbonates" @default.
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- W3129207375 doi "https://doi.org/10.3390/molecules26041089" @default.
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