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• W3129687125 abstract "Abstract All-solid-state batteries have been expected to overcome the safety problem of present lithium-ion batteries including organic liquid electrolytes. The materials with high ionic conductivity are urgently needed. In this paper, we reported a new ionic crystal Sr 2 Fe 8 O 18 which can be applicated on solid electrolyte. Sr 2 Fe 8 O 18 is a typical p-type semiconductor and shows a layered monoclinic crystal structure. The resistivities of Sr 2 Fe 8 O 18 in the temperature range of 20 ~ 145 °C were above 10 7 Ω•cm. The microstructure of Sr 2 Fe 8 O 18 was flaky, and the size of flaks were 1 µm ~ 5 µm. The E - P curve suggested that it was a ferroelectric semiconductor and had small ferroelectric effect. The dielectric response study (Cole-Cole plot) showed that Sr 2 Fe 8 O 18 had two separated relaxation time, each of which contained a group of relaxation. The ionic conductivity σ of the sample was calculated to be 0.2196 × 10 − 4 S/cm. The conductive mechanism which confirmed by the results of First principle calculation at 300K is mainly sublattice vacancy cation diffusion with self-diffusion coefficient D of 1.794 × 10 − 5 cm 2 /s. Fe ion has two dimensional diffusion path (x and y axial), and Sr ion has on dimensional diffusion path (x axial). The crystal structure of Sr 2 Fe 8 O 18 shows tremendous potential application on the solid electrolyte preparation." @default.
• W3129687125 created "2021-03-01" @default.
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• W3129687125 date "2020-12-22" @default.
• W3129687125 modified "2023-10-16" @default.
• W3129687125 title "A New Ceramic Sr2Fe8O18: Crystal Structure and Analysis of Application on Solid Electrolytes" @default.
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• W3129687125 doi "https://doi.org/10.21203/rs.3.rs-131868/v1" @default.
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