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- W3130187939 abstract "Stereoselective synthesis of natural and unnatural compounds containing the pyrrolizidine skeleton is of immense interest to synthetic organic chemists due to their enormous biological importance. In addition to the numerous total synthetic approaches, the development of direct synthetic strategies for the enantioselective preparation of pyrrolizidines has shown rapid progress in the last decade. The 1,3-dipolar cycloaddition reaction of a dipole and a dipolarophile has been found to be the most useful tool for the direct asymmetric synthesis of pyrrolizidines, and Michael addition followed by cyclisation is implicated for the preparation of pyrrolizidinones. In this digest review, we discuss the direct approaches for the preparation of optically active pyrrolizidines and pyrrolizidinones." @default.
- W3130187939 created "2021-03-01" @default.
- W3130187939 creator A5039951983 @default.
- W3130187939 creator A5071771773 @default.
- W3130187939 date "2021-04-01" @default.
- W3130187939 modified "2023-10-16" @default.
- W3130187939 title "Direct enantioselective synthesis of pyrrolizidines" @default.
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- W3130187939 doi "https://doi.org/10.1016/j.tetlet.2021.152954" @default.
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