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- W3130669837 abstract "Luminescence and structural properties of Pr3+ doped HfSiOx thin layer elaborated by magnetron sputtering have been investigated as a function of the annealing temperature. The emission properties of Pr3+ ions were studied using photoluminescence (PL) and cathodoluminescence (CL) spectroscopies. Phase separation between amorphous SiO2 and crystallized HfO2 nano-grains occurring in the HfSiOx matrix has been investigated by atom probe tomography and transmission electron microscopy with particular consideration for the Pr distribution. Both PL and CL measurements evidenced a strong emission originating from Pr3+ ions in the visible range for an annealing temperature higher than 950°C. At 950°C, Pr3+ ions are clearly located in HfO2 nano-grains of cubic structure. Regarding PL, no significant changes are observed between 950°C and 1050°C. However, CL measurements revealed new emission peaks in the infrared range after an annealing at 1050°C, corresponding to the appearance of a new orthorhombic crystalline structure of HfO2 nano-grains in the thin layer. The CL signal evolution as a function of the annealing treatment is discussed in regard to the evolution of structural properties." @default.
- W3130669837 created "2021-03-01" @default.
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- W3130669837 date "2021-07-01" @default.
- W3130669837 modified "2023-10-18" @default.
- W3130669837 title "Correlation of luminescence measurements to the structural characterization of Pr3+-doped HfSiOx" @default.
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- W3130669837 doi "https://doi.org/10.1016/j.jlumin.2021.118004" @default.
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