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- W3130894311 abstract "Abstract Vetiver oil, produced on a multiton‐scale from the roots of vetiver grass, is one of the finest and most popular perfumery materials, appearing in over a third of all fragrances. It is a complex mixture of hundreds of molecules and the specific odorant, responsible for its characteristic suave and sweet transparent, woody‐ambery smell, has remained a mystery until today. Herein, we prove by an eleven‐step chemical synthesis, employing a novel asymmetric organocatalytic Mukaiyama–Michael addition, that (+)‐2‐epi‐ziza‐6(13)en‐3‐one is the active smelling principle of vetiver oil. Its olfactory evaluation reveals a remarkable odor threshold of 29 picograms per liter air, responsible for the special sensuous aura it lends to perfumes and the quasi‐pheromone‐like effect it has on perfumers and consumers alike." @default.
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- W3130894311 date "2021-02-09" @default.
- W3130894311 modified "2023-10-17" @default.
- W3130894311 title "The Smelling Principle of Vetiver Oil, Unveiled by Chemical Synthesis" @default.
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- W3130894311 doi "https://doi.org/10.1002/anie.202014609" @default.
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