Matches in SemOpenAlex for { <https://semopenalex.org/work/W3131034276> ?p ?o ?g. }
- W3131034276 endingPage "201" @default.
- W3131034276 startingPage "193" @default.
- W3131034276 abstract "Formic acid (FA) is a promising hydrogen carrier which can play an instrumental role in the overall implementation of a hydrogen economy. In this regard, it is important to generate H2 gas from neat FA without any solvent/additive, for which existing systems are scarce. Here we report the remarkable catalytic activity of a ruthenium 9H-acridine pincer complex for this process. The catalyst is unusually stable and robust in FA even at high temperatures and can catalyse neat FA dehydrogenation for over a month, with a total turnover number of 1,701,150, while also generating high H2/CO2 gas pressures (tested up to 100 bars). Mechanistic investigations and DFT studies are conducted to fully understand the molecular mechanism to the process. Overall, the high activity, stability, selectivity, simplicity and versatility of the system to generate a CO-free H2/CO2 gas stream and high pressure from neat FA makes it promising for large-scale implementation." @default.
- W3131034276 created "2021-03-01" @default.
- W3131034276 creator A5009936068 @default.
- W3131034276 creator A5044382784 @default.
- W3131034276 creator A5049737397 @default.
- W3131034276 creator A5077738224 @default.
- W3131034276 creator A5081692819 @default.
- W3131034276 date "2021-02-22" @default.
- W3131034276 modified "2023-10-17" @default.
- W3131034276 title "Highly efficient additive-free dehydrogenation of neat formic acid" @default.
- W3131034276 cites W1970623278 @default.
- W3131034276 cites W1981807278 @default.
- W3131034276 cites W1988091937 @default.
- W3131034276 cites W2011215428 @default.
- W3131034276 cites W2021996077 @default.
- W3131034276 cites W2092157292 @default.
- W3131034276 cites W2097957611 @default.
- W3131034276 cites W2119547517 @default.
- W3131034276 cites W2129993089 @default.
- W3131034276 cites W2140156540 @default.
- W3131034276 cites W2142527379 @default.
- W3131034276 cites W2143828944 @default.
- W3131034276 cites W2150195378 @default.
- W3131034276 cites W2158195600 @default.
- W3131034276 cites W2166276784 @default.
- W3131034276 cites W2166296697 @default.
- W3131034276 cites W2168768221 @default.
- W3131034276 cites W2169897770 @default.
- W3131034276 cites W2313038642 @default.
- W3131034276 cites W2327617832 @default.
- W3131034276 cites W2332371349 @default.
- W3131034276 cites W2332611934 @default.
- W3131034276 cites W2336998050 @default.
- W3131034276 cites W2340063144 @default.
- W3131034276 cites W2342502077 @default.
- W3131034276 cites W2418973097 @default.
- W3131034276 cites W2470745431 @default.
- W3131034276 cites W2522536116 @default.
- W3131034276 cites W2524870669 @default.
- W3131034276 cites W2560407024 @default.
- W3131034276 cites W2560894534 @default.
- W3131034276 cites W2561072936 @default.
- W3131034276 cites W2565870685 @default.
- W3131034276 cites W2567784893 @default.
- W3131034276 cites W2617859884 @default.
- W3131034276 cites W2626025588 @default.
- W3131034276 cites W2739439285 @default.
- W3131034276 cites W2761959175 @default.
- W3131034276 cites W2765962542 @default.
- W3131034276 cites W2783193707 @default.
- W3131034276 cites W2793696306 @default.
- W3131034276 cites W2797673087 @default.
- W3131034276 cites W2891908446 @default.
- W3131034276 cites W2896677470 @default.
- W3131034276 cites W2897474176 @default.
- W3131034276 cites W2897943214 @default.
- W3131034276 cites W2901515114 @default.
- W3131034276 cites W2913460818 @default.
- W3131034276 cites W2944437634 @default.
- W3131034276 cites W2955267624 @default.
- W3131034276 cites W2974417975 @default.
- W3131034276 cites W2999884083 @default.
- W3131034276 cites W3005067277 @default.
- W3131034276 cites W3005456665 @default.
- W3131034276 cites W3006183697 @default.
- W3131034276 cites W3011043122 @default.
- W3131034276 cites W4211160248 @default.
- W3131034276 doi "https://doi.org/10.1038/s41929-021-00575-4" @default.
- W3131034276 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/37152186" @default.
- W3131034276 hasPublicationYear "2021" @default.
- W3131034276 type Work @default.
- W3131034276 sameAs 3131034276 @default.
- W3131034276 citedByCount "79" @default.
- W3131034276 countsByYear W31310342762021 @default.
- W3131034276 countsByYear W31310342762022 @default.
- W3131034276 countsByYear W31310342762023 @default.
- W3131034276 crossrefType "journal-article" @default.
- W3131034276 hasAuthorship W3131034276A5009936068 @default.
- W3131034276 hasAuthorship W3131034276A5044382784 @default.
- W3131034276 hasAuthorship W3131034276A5049737397 @default.
- W3131034276 hasAuthorship W3131034276A5077738224 @default.
- W3131034276 hasAuthorship W3131034276A5081692819 @default.
- W3131034276 hasBestOaLocation W31310342762 @default.
- W3131034276 hasConcept C118792377 @default.
- W3131034276 hasConcept C119889771 @default.
- W3131034276 hasConcept C127413603 @default.
- W3131034276 hasConcept C161790260 @default.
- W3131034276 hasConcept C178790620 @default.
- W3131034276 hasConcept C185592680 @default.
- W3131034276 hasConcept C21951064 @default.
- W3131034276 hasConcept C2776924795 @default.
- W3131034276 hasConcept C2777379063 @default.
- W3131034276 hasConcept C42360764 @default.
- W3131034276 hasConcept C512968161 @default.
- W3131034276 hasConcept C555196967 @default.
- W3131034276 hasConcept C73969872 @default.
- W3131034276 hasConcept C91819851 @default.
- W3131034276 hasConceptScore W3131034276C118792377 @default.