Matches in SemOpenAlex for { <https://semopenalex.org/work/W3131716507> ?p ?o ?g. }
- W3131716507 endingPage "4660" @default.
- W3131716507 startingPage "4653" @default.
- W3131716507 abstract "Metal carbenes are key intermediates in a plethora of homogeneous and heterogeneous catalytic processes. However, despite their importance to heterogeneous catalysis, the influence of surface attachment on carbene reactivity has not yet been explored. Here, we reveal the interactions of fluorenylidene (FY), an archetypical aromatic carbene of extreme reactivity, with a Ag(111) surface. For the first time, the interaction of a highly reactive carbene with a metal surface could be studied by scanning tunneling microscopy (STM). FY chemisorbs on Ag(111) with an estimated desorption energy of 3 eV, forming a surface bound silver-carbene complex. The surface interaction leads to a switching of the electronic ground state of FY from triplet to singlet, and to controlled chemical reactivity. This atomistic understanding of the interplay between carbenes and metal surfaces opens the way for the development of novel classes of catalytic systems based on surface metal carbenes." @default.
- W3131716507 created "2021-03-01" @default.
- W3131716507 creator A5011649967 @default.
- W3131716507 creator A5016664068 @default.
- W3131716507 creator A5041210815 @default.
- W3131716507 creator A5052891474 @default.
- W3131716507 creator A5058448605 @default.
- W3131716507 creator A5088456882 @default.
- W3131716507 date "2021-02-18" @default.
- W3131716507 modified "2023-10-18" @default.
- W3131716507 title "Controlling Reactivity—Real-Space Imaging of a Surface Metal Carbene" @default.
- W3131716507 cites W1967253297 @default.
- W3131716507 cites W1994652456 @default.
- W3131716507 cites W1996179939 @default.
- W3131716507 cites W2009381692 @default.
- W3131716507 cites W2021911325 @default.
- W3131716507 cites W2024876777 @default.
- W3131716507 cites W2025347444 @default.
- W3131716507 cites W2035058396 @default.
- W3131716507 cites W2036820781 @default.
- W3131716507 cites W2048807254 @default.
- W3131716507 cites W2050362249 @default.
- W3131716507 cites W2052755153 @default.
- W3131716507 cites W2054704030 @default.
- W3131716507 cites W2055817246 @default.
- W3131716507 cites W2056320353 @default.
- W3131716507 cites W2056341731 @default.
- W3131716507 cites W2069813563 @default.
- W3131716507 cites W2077875027 @default.
- W3131716507 cites W2091291116 @default.
- W3131716507 cites W2092157292 @default.
- W3131716507 cites W2099708381 @default.
- W3131716507 cites W2112310839 @default.
- W3131716507 cites W2113838719 @default.
- W3131716507 cites W2149783350 @default.
- W3131716507 cites W2154293001 @default.
- W3131716507 cites W2156307068 @default.
- W3131716507 cites W2156940754 @default.
- W3131716507 cites W2301697910 @default.
- W3131716507 cites W2314517829 @default.
- W3131716507 cites W2318070927 @default.
- W3131716507 cites W2324825323 @default.
- W3131716507 cites W2334206830 @default.
- W3131716507 cites W2514267515 @default.
- W3131716507 cites W2529458179 @default.
- W3131716507 cites W2599737618 @default.
- W3131716507 cites W2760236415 @default.
- W3131716507 cites W2807103090 @default.
- W3131716507 cites W2891012095 @default.
- W3131716507 cites W2897876811 @default.
- W3131716507 cites W2907475559 @default.
- W3131716507 cites W2950351456 @default.
- W3131716507 cites W2968969098 @default.
- W3131716507 cites W3004603660 @default.
- W3131716507 cites W3004625275 @default.
- W3131716507 cites W3014491440 @default.
- W3131716507 cites W4237875027 @default.
- W3131716507 cites W4240676900 @default.
- W3131716507 cites W4251485118 @default.
- W3131716507 cites W2951251393 @default.
- W3131716507 doi "https://doi.org/10.1021/jacs.0c12995" @default.
- W3131716507 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33599124" @default.
- W3131716507 hasPublicationYear "2021" @default.
- W3131716507 type Work @default.
- W3131716507 sameAs 3131716507 @default.
- W3131716507 citedByCount "8" @default.
- W3131716507 countsByYear W31317165072022 @default.
- W3131716507 countsByYear W31317165072023 @default.
- W3131716507 crossrefType "journal-article" @default.
- W3131716507 hasAuthorship W3131716507A5011649967 @default.
- W3131716507 hasAuthorship W3131716507A5016664068 @default.
- W3131716507 hasAuthorship W3131716507A5041210815 @default.
- W3131716507 hasAuthorship W3131716507A5052891474 @default.
- W3131716507 hasAuthorship W3131716507A5058448605 @default.
- W3131716507 hasAuthorship W3131716507A5088456882 @default.
- W3131716507 hasConcept C138885662 @default.
- W3131716507 hasConcept C142724271 @default.
- W3131716507 hasConcept C161790260 @default.
- W3131716507 hasConcept C178790620 @default.
- W3131716507 hasConcept C185592680 @default.
- W3131716507 hasConcept C204787440 @default.
- W3131716507 hasConcept C2524010 @default.
- W3131716507 hasConcept C2776799497 @default.
- W3131716507 hasConcept C2776910235 @default.
- W3131716507 hasConcept C2777164566 @default.
- W3131716507 hasConcept C2778572836 @default.
- W3131716507 hasConcept C33923547 @default.
- W3131716507 hasConcept C41895202 @default.
- W3131716507 hasConcept C544153396 @default.
- W3131716507 hasConcept C71924100 @default.
- W3131716507 hasConceptScore W3131716507C138885662 @default.
- W3131716507 hasConceptScore W3131716507C142724271 @default.
- W3131716507 hasConceptScore W3131716507C161790260 @default.
- W3131716507 hasConceptScore W3131716507C178790620 @default.
- W3131716507 hasConceptScore W3131716507C185592680 @default.
- W3131716507 hasConceptScore W3131716507C204787440 @default.
- W3131716507 hasConceptScore W3131716507C2524010 @default.
- W3131716507 hasConceptScore W3131716507C2776799497 @default.