Matches in SemOpenAlex for { <https://semopenalex.org/work/W3131902010> ?p ?o ?g. }
- W3131902010 abstract "Styrene is an important commodity chemical that is highly energy and CO2 intensive to produce. We report a redox oxidative dehydrogenation (redox-ODH) strategy to efficiently produce styrene. Facilitated by a multifunctional (Ca/Mn)1-xO@KFeO2 core-shell redox catalyst which acts as (i) a heterogeneous catalyst, (ii) an oxygen separation agent, and (iii) a selective hydrogen combustion material, redox-ODH auto-thermally converts ethylbenzene to styrene with up to 97% single-pass conversion and >94% selectivity. This represents a 72% yield increase compared to commercial dehydrogenation on a relative basis, leading to 82% energy savings and 79% CO2 emission reduction. The redox catalyst is composed of a catalytically active KFeO2 shell and a (Ca/Mn)1-xO core for reversible lattice oxygen storage and donation. The lattice oxygen donation from (Ca/Mn)1-xO sacrificially stabilizes Fe3+ in the shell to maintain high catalytic activity and coke resistance. From a practical standpoint, the redox catalyst exhibits excellent long-term performance under industrially compatible conditions." @default.
- W3131902010 created "2021-03-01" @default.
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- W3131902010 date "2021-02-26" @default.
- W3131902010 modified "2023-10-17" @default.
- W3131902010 title "A tailored multi-functional catalyst for ultra-efficient styrene production under a cyclic redox scheme" @default.
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- W3131902010 doi "https://doi.org/10.1038/s41467-021-21374-2" @default.
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