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• W3132085872 abstract "The title diorganotin Schiff base derivative, [Sn(C 4 H 9 ) 2 (C 15 H 13 N 3 O 2 S)], features a penta-coordinated tin centre defined by the N, O , S -donor atoms of the di-anionic Schiff base ligand and two methylene-C atoms of the n -butyl substituents. The resultant C 2 NOS donor set defines a geometry intermediate between trigonal–bipyramidal and square-pyramidal. In the crystal, amine-N—H...O(methoxy) hydrogen bonding is found in a helical, supramolecular chain propagating along the b -axis direction. The chains are assembled into a layer parallel to (overline{1}01) with methylene-C—H...π(phenyl) interactions prominent; layers stack without directional interactions between them. The analysis of the calculated Hirshfeld surface showed the presence of weak methylene-C—H...π(phenyl) interactions and short H...H contacts in the inter-layer region. Consistent with the nature of the identified contacts, the stabilization of the crystal is dominated by the dispersion energy term." @default.
• W3132085872 created "2021-03-01" @default.
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• W3132085872 date "2021-02-23" @default.
• W3132085872 modified "2023-09-24" @default.
• W3132085872 title "Di-n-butyl[N′-(3-methoxy-2-oxidobenzylidene)-N-phenylcarbamohydrazonothioato]tin(IV): crystal structure, Hirshfeld surface analysis and computational study" @default.
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• W3132085872 doi "https://doi.org/10.1107/s2056989021001870" @default.
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