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- W3132230186 abstract "Acoustic cavitation is the central event of water sonolysis, which generates several radical and nonradical species such as H•, •OH, H2, and H2O2. In addition to these species, production of HNO2 and HNO3 was demonstrated in N2-containing aqueous solutions. These species were usually liberated as nitrite and nitrate ions. The mechanism by which NO2− and NO3− are formed is until now under discussion. Many researchers reported that both species are formed in the gas phase of the bubble and diffused out into the surrounding liquid. Other ones claimed that NO2− and NO3− are both formed at the bubble–solution interface and in the solution bulk. A third part suggested that the gas phase reaction is the source of HNO2, while a part of the nitrite is oxidized to nitrate in the solution. In this chapter, we attempt to discuss the mechanism and the reaction zone of nitrite and nitrate formation during water sonolysis by adopting a new approach based on predicting the overall acoustic generation rates of HNO2 and HNO3 and comparing them with experimental measurements. A single-bubble sonochemistry model was used for predicting the yields of HNO2 and HNO3 from a single collapsing bubble under various operating conditions. Our findings support the fact that HNO2 is predominately formed during the gas phase reaction inside the bubble and diffused into the liquid to liberate NO2−, whereas HNO3 (NO3−) could be formed at the liquid shell of the bubble and in the bulk of solution through several reaction pathways." @default.
- W3132230186 created "2021-03-01" @default.
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- W3132230186 date "2021-01-01" @default.
- W3132230186 modified "2023-09-25" @default.
- W3132230186 title "On the sonochemical production of nitrite and nitrate in water: A computational study" @default.
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- W3132230186 doi "https://doi.org/10.1016/b978-0-12-820644-7.00017-7" @default.
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