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- W3132328529 endingPage "10908" @default.
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- W3132328529 abstract "Abstract The poor electrical conductivity of two‐dimensional (2D) crystalline frameworks greatly limits their utilization in optoelectronics and sensor technology. Herein, we describe a conductive metallophthalocyanine‐based NiPc‐CoTAA framework with cobalt(II) tetraaza[14]annulene linkages. The high conjugation across the whole network combined with densely stacked metallophthalocyanine units endows this material with high electrical conductivity, which can be greatly enhanced by doping with iodine. The NiPc‐CoTAA framework was also fabricated as thin films with different thicknesses from 100 to 1000 nm by the steam‐assisted conversion method. These films enabled the detection of low‐concentration gases and exhibited remarkable sensitivity and stability. This study indicates the enormous potential of metallophthalocyanine‐based conductive frameworks in advanced stand‐off chemical sensors and provides a general strategy through tailor‐make molecular design to develop sensitive and stable chemical sensors for the detection of low‐concentration gases." @default.
- W3132328529 created "2021-03-01" @default.
- W3132328529 creator A5018451658 @default.
- W3132328529 creator A5035298559 @default.
- W3132328529 creator A5050051276 @default.
- W3132328529 creator A5050718596 @default.
- W3132328529 creator A5065852087 @default.
- W3132328529 creator A5066043968 @default.
- W3132328529 creator A5084176696 @default.
- W3132328529 date "2021-04-01" @default.
- W3132328529 modified "2023-09-26" @default.
- W3132328529 title "Conductive Metallophthalocyanine Framework Films with High Carrier Mobility as Efficient Chemiresistors" @default.
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