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- W3132362223 abstract "A cascade approach to the synthesis of 5-(indol-3-yl)hydantoin framework has been developed by the reaction of indole with glyoxylic acid/pyruvic acid under a deep eutectic solution, (+)-tartaric acid-dimethylurea. N,N'-Dimethylurea from a deep eutectic solution functions as a reactant as well as a solvent mixture. Isolation of the intermediate, 5-hydroxyhydantoin, and its reaction with indole provides the mechanistic evidence for this reaction. This method was successfully applied in the first total synthesis of an alkaloid, (±)-oxoaplysinopsin B, with an overall yield of 48%." @default.
- W3132362223 created "2021-03-01" @default.
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- W3132362223 creator A5052877130 @default.
- W3132362223 creator A5061072460 @default.
- W3132362223 date "2021-02-18" @default.
- W3132362223 modified "2023-10-18" @default.
- W3132362223 title "A Cascade Approach for the Synthesis of 5-(Indol-3-yl)hydantoin: An Application to the Total Synthesis of (±)-Oxoaplysinopsin B" @default.
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- W3132362223 doi "https://doi.org/10.1021/acs.joc.0c02435" @default.
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