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- W3132460981 endingPage "033602" @default.
- W3132460981 startingPage "033602" @default.
- W3132460981 abstract "The temperature coefficient α (= dV/dT) of the redox potential (V) in a redox system, or so-called electrochemical Seebeck coefficient, is a key parameter for thermal energy harvesting. We systematically investigated α for Fe2+/Fe3+ in 16 organic solvents, i.e., 8 protic and 8 aprotic solvents. We found that α shows remarkable solvent dependence and is distributed from 0.14 mV/K for glycerin to 3.60 mV/K for acetone. We further found a scaling relation between α and viscosity (η) of the solvent as α ∝ η−0.4. We will discuss solvent dependence of α and the scaling relation in terms of the configuration entropy of the solvent molecules." @default.
- W3132460981 created "2021-03-01" @default.
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- W3132460981 date "2021-03-15" @default.
- W3132460981 modified "2023-10-17" @default.
- W3132460981 title "Scaling Relation between Electrochemical Seebeck Coefficient for Fe<sup>2+</sup>/Fe<sup>3+</sup> in Organic Solvent and Its Viscosity" @default.
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- W3132460981 doi "https://doi.org/10.7566/jpsj.90.033602" @default.
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