FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3132879389> ?p ?o ?g. }

• W3132879389 endingPage "110331" @default.
• W3132879389 startingPage "110331" @default.
• W3132879389 abstract "In this article, the free radical polymerization of acrylates was successfully achieved with a series of twelve push-pull chromophores comprising the N-ethyl carbazole-1-allylidene group as the electron-donating group. Using this strong donor, the resulting dyes, never synthesized before, could efficiently initiate the free radical photopolymerization of acrylates upon mild irradiation conditions e.g. using sunlight. These novel multi-component systems comprising the above mentioned push-pull dyes, a tertiary amine (ethyl dimethylaminobenzoate EDB) and an iodonium salt could act as efficient photoinitiating systems (PISs) in free radical polymerization (FRP), leading to the formation of 3D patterns with precise shapes under the direct laser write (DLW) approach. Among these new PISs, dyes 3, 6, 7 and 8 were selected due to their efficient photoinitiation performances for chemical mechanism studies including steady state photolysis, fluorescence quenching measurements, electron spin resonance (ESR) spin-trapping experiments and cyclic voltammetry. Markedly, their excellent photochemical reactivities prompted us to investigate the performance of these multi-component photoinitiating systems upon sunlight as an ecofriendly approach. As a result, this research proved that sunlight could be used as a potential light source that can advantageously replace LEDs when highly reactive push-pull dyes are used as photosensitizers for the free radical photopolymerization of acrylate resins. Finally, 3D patterns could be prepared with the new photocomposites, and silica fillers could be even incorporated within the photosensitive resins so that a gradient of resolution could be successfully demonstrated." @default.
• W3132879389 created "2021-03-01" @default.
• W3132879389 creator A5037272156 @default.
• W3132879389 creator A5043838216 @default.
• W3132879389 creator A5055198364 @default.
• W3132879389 creator A5064530138 @default.
• W3132879389 creator A5071731562 @default.
• W3132879389 creator A5076071968 @default.
• W3132879389 creator A5078502925 @default.
• W3132879389 creator A5079933574 @default.
• W3132879389 creator A5083008558 @default.
• W3132879389 creator A5089956119 @default.
• W3132879389 date "2021-03-01" @default.
• W3132879389 modified "2023-10-13" @default.
• W3132879389 title "N-ethyl carbazole-1-allylidene-based push-pull dyes as efficient light harvesting photoinitiators for sunlight induced polymerization" @default.
• W3132879389 cites W1963797980 @default.
• W3132879389 cites W1964305430 @default.
• W3132879389 cites W1973221314 @default.
• W3132879389 cites W1976401432 @default.
• W3132879389 cites W1979961582 @default.
• W3132879389 cites W1990834214 @default.
• W3132879389 cites W1999011575 @default.
• W3132879389 cites W2009540782 @default.
• W3132879389 cites W2015549218 @default.
• W3132879389 cites W2020439189 @default.
• W3132879389 cites W2030643245 @default.
• W3132879389 cites W2031525746 @default.
• W3132879389 cites W2032065892 @default.
• W3132879389 cites W2037915777 @default.
• W3132879389 cites W2040387656 @default.
• W3132879389 cites W2046435506 @default.
• W3132879389 cites W2048188558 @default.
• W3132879389 cites W2073052266 @default.
• W3132879389 cites W2073568840 @default.
• W3132879389 cites W2081903700 @default.
• W3132879389 cites W2090724481 @default.
• W3132879389 cites W2098860971 @default.
• W3132879389 cites W2107224343 @default.
• W3132879389 cites W2145773666 @default.
• W3132879389 cites W2151138497 @default.
• W3132879389 cites W2154365212 @default.
• W3132879389 cites W2157788244 @default.
• W3132879389 cites W2166891349 @default.
• W3132879389 cites W2316847271 @default.
• W3132879389 cites W2321434322 @default.
• W3132879389 cites W2322354512 @default.
• W3132879389 cites W2326456343 @default.
• W3132879389 cites W2327931957 @default.
• W3132879389 cites W2331900031 @default.
• W3132879389 cites W2333686151 @default.
• W3132879389 cites W2520547465 @default.
• W3132879389 cites W2524848750 @default.
• W3132879389 cites W2529854953 @default.
• W3132879389 cites W2547132653 @default.
• W3132879389 cites W2563699356 @default.
• W3132879389 cites W2755234047 @default.
• W3132879389 cites W2757103680 @default.
• W3132879389 cites W2762875226 @default.
• W3132879389 cites W2777072594 @default.
• W3132879389 cites W2886370720 @default.
• W3132879389 cites W2889949819 @default.
• W3132879389 cites W2902580257 @default.
• W3132879389 cites W2936405479 @default.
• W3132879389 cites W2936653243 @default.
• W3132879389 cites W2940826291 @default.
• W3132879389 cites W2951347763 @default.
• W3132879389 cites W2980806679 @default.
• W3132879389 cites W2989859051 @default.
• W3132879389 cites W2998201521 @default.
• W3132879389 cites W3000599898 @default.
• W3132879389 cites W3018861205 @default.
• W3132879389 cites W3082971499 @default.
• W3132879389 cites W3094354228 @default.
• W3132879389 doi "https://doi.org/10.1016/j.eurpolymj.2021.110331" @default.
• W3132879389 hasPublicationYear "2021" @default.
• W3132879389 type Work @default.
• W3132879389 sameAs 3132879389 @default.
• W3132879389 citedByCount "37" @default.
• W3132879389 countsByYear W31328793892021 @default.
• W3132879389 countsByYear W31328793892022 @default.
• W3132879389 countsByYear W31328793892023 @default.
• W3132879389 crossrefType "journal-article" @default.
• W3132879389 hasAuthorship W3132879389A5037272156 @default.
• W3132879389 hasAuthorship W3132879389A5043838216 @default.
• W3132879389 hasAuthorship W3132879389A5055198364 @default.
• W3132879389 hasAuthorship W3132879389A5064530138 @default.
• W3132879389 hasAuthorship W3132879389A5071731562 @default.
• W3132879389 hasAuthorship W3132879389A5076071968 @default.
• W3132879389 hasAuthorship W3132879389A5078502925 @default.
• W3132879389 hasAuthorship W3132879389A5079933574 @default.
• W3132879389 hasAuthorship W3132879389A5083008558 @default.
• W3132879389 hasAuthorship W3132879389A5089956119 @default.
• W3132879389 hasBestOaLocation W31328793891 @default.
• W3132879389 hasConcept C111998727 @default.
• W3132879389 hasConcept C121332964 @default.
• W3132879389 hasConcept C121745418 @default.
• W3132879389 hasConcept C123669783 @default.
• W3132879389 hasConcept C15487406 @default.

• next