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• W3133272103 abstract "Reported herein are the synthesis and structures of two high-nuclearity AuAg nanoclusters, namely, [Au78Ag66(C≡CPh)48Cl8]q− and [Au74Ag60(C≡CPh)40Br12]2–. Both clusters possess a three-concentric-shell Au12@Au42@Ag60 structure. However, the dispositions of the metal atoms, and the ligand coordination modes, of the outermost shells of these clusters are distinctly different. These structural differences reflect the bonding characteristics of the halide ligands. As revealed by density functional theory analysis, these clusters exhibit superatomic electron shell closings at magic numbers of 92 (for q = 4) and 84, respectively, consistent with their spherical shapes. Both clusters exhibit unusual multivalent redox properties." @default.
• W3133272103 created "2021-03-01" @default.
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• W3133272103 date "2021-02-21" @default.
• W3133272103 modified "2023-10-10" @default.
• W3133272103 title "Atomically Precise Alkynyl- and Halide-Protected AuAg Nanoclusters Au₇₈Ag₆₆(C≡CPh)₄₈Cl₈ and Au₇₄Ag₆₀(C≡CPh)₄₀Br₁₂: The Ligation Effects of Halides" @default.
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• W3133272103 doi "https://doi.org/10.1021/acs.inorgchem.0c03462" @default.
• W3133272103 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33615777" @default.
• W3133272103 hasPublicationYear "2021" @default.
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