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- W3133444865 endingPage "530" @default.
- W3133444865 startingPage "508" @default.
- W3133444865 abstract "Mechanically interlocked polymers (MIPs), such as polyrotaxanes and polycatenanes, are polymer architectures that incorporate a mechanical bond. In a polyrotaxane, the mechanical bond is the result of a linear dumbbell component threaded through a ring, while in a polycatenane, it is the consequence of interlocked ring components. The interlocked nature of these architectures can result in high degrees of conformational freedom and mobility of their components, which can give rise to unique property profiles. In recent years, the synthesis and studies of a range of MIPs has allowed researchers to build an initial understanding of how incorporating mechanical bonds within a polymer structure impacts its material properties. This Review focuses on the understanding of these structure–property relationships with an outlook towards their applications, specifically focusing on four main classes of MIPs: polyrotaxanes, slide-ring gels, daisy-chain polymers and polycatenanes. Incorporating the mechanical bond into polymer architectures allows access to polymers with high-mobility elements, leading to unique material properties. This Review outlines the structure–property relationships of materials based on either polyrotaxanes (including slide-ring materials and daisy-chain polymers) or polycatenanes, and looks towards future applications and technologies." @default.
- W3133444865 created "2021-03-01" @default.
- W3133444865 creator A5003491327 @default.
- W3133444865 creator A5004881644 @default.
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- W3133444865 creator A5035361360 @default.
- W3133444865 creator A5057036430 @default.
- W3133444865 creator A5064617897 @default.
- W3133444865 date "2021-02-12" @default.
- W3133444865 modified "2023-10-11" @default.
- W3133444865 title "Material properties and applications of mechanically interlocked polymers" @default.
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