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- W3133788835 endingPage "115758" @default.
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- W3133788835 abstract "An efficient and sustainable protocol for the hydration of alkynes has been developed under metal/acid/catalyst/ligand-free conditions in a water/ethyl lactate mixture. The hydrogen-bond network in the ethyl lactate and water mixture plays a crucial and decisive role in activating the alkynes for hydration to afford the corresponding methyl ketones. This strategy gives the Markovnikov (ketone) addition product selectively over other possible products. The essential role of hydrogen bonding has been confirmed by experimental and theoretical techniques. A probable mechanism has been suggested by various control tests. The efficacy of the method has been further explored for the competent production of value-added α,β-unsaturated carbonyl compounds through the reaction of aldehydes with alkynes as ketonic surrogates. The environmentally benign hydration method takes place under mild conditions, has broad functional-group compatibility, and uses the ethyl lactate/water (1:3) medium as a “green alternative” in the absence of any hazardous, harmful, or expensive substances." @default.
- W3133788835 created "2021-03-15" @default.
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- W3133788835 date "2021-06-01" @default.
- W3133788835 modified "2023-10-03" @default.
- W3133788835 title "Catalyst- and acid-free Markovnikov hydration of alkynes in a sustainable H2O/ethyl lactate system" @default.
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- W3133788835 doi "https://doi.org/10.1016/j.molliq.2021.115758" @default.
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