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- W3133969312 abstract "Abstract The development of a novel heterogeneous polymer supported palladium catalyst for the oxidative C−H olefination of anilides is described. The catalyst was realized by immobilizing Palladium acetate over ethylene diamine modified Polyacrylonitrile (PAN) and characterized by means of FTIR, XRD and XPS analyses which evidenced the complexation of Pd(OAc) 2 with the chelating groups in the polymer. The resulting supported complex (en‐PAN‐Pd) was then explored as an efficient and reusable heterogeneous catalyst for ortho selective C−H activation of anilides on reaction with a number of alkyl acrylates. This reaction protocol serves as a useful and greener method for the synthesis of o ‐alkenyl anilides under mild reaction conditions. The catalyst also exhibited good recyclability and reusability without losing much catalytic activity." @default.
- W3133969312 created "2021-03-15" @default.
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- W3133969312 date "2021-03-10" @default.
- W3133969312 modified "2023-10-12" @default.
- W3133969312 title "An Efficient Polymer Supported Palladium Catalyst for <i>ortho</i> Selective C−H Olefination of Anilides" @default.
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- W3133969312 doi "https://doi.org/10.1002/slct.202100052" @default.
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