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- W3134082893 endingPage "132051" @default.
- W3134082893 startingPage "132051" @default.
- W3134082893 abstract "The alkylation of a variety of ketones using 1° or 2° alcohols under hydrogen borrowing catalysis is described. Initial research focused on the α-alkylation of cyclopropyl ketones with higher 1° alcohols (i.e. larger than MeOH), leading to the formation of α-branched products. Our search for additional substrates with which to explore this chemistry led us to discover that di- ortho -substituted aryl ketones were also privileged scaffolds, with Ph∗ (C 6 Me 5 ) ketones being the optimal choice. Further investigations revealed that this motif was crucial for alkylation with 2° alcohols forming β-branched products, which also provided an opportunity to study diastereoselective and intramolecular hydrogen borrowing processes." @default.
- W3134082893 created "2021-03-15" @default.
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- W3134082893 date "2021-04-01" @default.
- W3134082893 modified "2023-09-25" @default.
- W3134082893 title "Hydrogen borrowing catalysis using 1° and 2° alcohols: Investigation and scope leading to α and β branched products" @default.
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- W3134082893 doi "https://doi.org/10.1016/j.tet.2021.132051" @default.
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