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- W3134626033 endingPage "138064" @default.
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- W3134626033 abstract "• Donor-acceptor-donor type systems bearing POSS unit were synthesized and polymerized. • Thiophene and alkylenedioxythiophene derivatives were used as donor units. • EDOT derivative and its polymer showed the lowest oxidation and band gap values. • Effect of substituents can be observed on the polymer properties. • Polymers exhibited some properties like ion sensing, electrochromism and stability. • Polymers can be used in electro-optic devices and sensors. A series of new donor-acceptor-donor type fluorescent molecules incorporating thieno[3,4- c ]pyrrole-4,6‑dione (TPD) as the acceptor unit were synthesized. TPD acceptor unit was modified with polyhedral oligomeric silsesquioxanes (POSS) cages and integrated with thiophene and alkylenedioxythiophene derivatives (3,4-ethylenedioxythiophene (EDOT) and 3,4-propylenedioxythiophene (ProDOT)) using Stille coupling reaction. The monomers, T 2 -POSS, E 2 -POSS , and P 2 -POSS , were polymerized successfully via electrochemical and chemical polymerization techniques. As a fingerprint of d -A-D monomers, all monomers showed dual band characteristics due to intramolecular charge transfer. Soluble polymers exhibited reversible electrochromic responses electrochemically and chemically with fast switching times and high coloration efficiencies. E 2 -POSS and its polymer PE 2 -POSS exhibited the lowest oxidation potential and band gap values as compared to their thiophene and ProDOT analogs. Also, P 2 -POSS and its chemically obtained fluorescent polymer PP 2 -POSS-C represented high sensitivity towards Fe 2+ and Fe 3+ ions, which makes them potential candidates to be amenable for use in ion sensing." @default.
- W3134626033 created "2021-03-15" @default.
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- W3134626033 date "2021-05-01" @default.
- W3134626033 modified "2023-09-24" @default.
- W3134626033 title "Polyhedral oligomeric silsesquioxanes appended conjugated soluble polymers based on thieno[3,4-c]pyrrole-4,6‑dione acceptor unit" @default.
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- W3134626033 doi "https://doi.org/10.1016/j.electacta.2021.138064" @default.
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