Matches in SemOpenAlex for { <https://semopenalex.org/work/W3134712705> ?p ?o ?g. }
- W3134712705 endingPage "5268" @default.
- W3134712705 startingPage "5260" @default.
- W3134712705 abstract "Coupling between plasmonic nanoparticles (NPs) in nanoparticle assemblies has been investigated extensively via far-field properties, such as absorption and scattering, but very rarely via near-field properties, and a quantitative investigation of near-field properties should provide great insight into the nature of the coupling. We report a numerical procedure to obtain reliable near-field spectra (QNF) around spherical gold nanoparticles (Au NPs) using Discrete Dipole Approximation (DDA). The reliability of the method was tested by comparing QNF from DDA calculations with exact results from the Mie theory. We then applied the method to examine Au NPs assembled in dimer, trimer, and up to pentamer in a linear arrangement. For the well-studied dimer system, we show that the QNF enhancement, due to coupling in longitudinal mode, is much greater than the enhancement in Qext. There is a linear correlation between the QNF and Qext peak positions, with the QNF peak redshifted from the Qext peak by an average of approximately 12 nm. In the case of the multimers, QNF spectra from individual spheres were not always identical and become dependent on the sphere location. In the longitudinal model, the center sphere has the strongest QNF spectra. For the transverse mode, we differentiate two different scenario, transverse-Y where both electric field (E) and light propagation vector (k) are perpendicular the chain axis, and transverse-X where k is parallel to the chain axis. In transverse-Y mode, coupling leads to reduced QNF spectra and the center sphere has the lowest QNF intensity. In transverse-X mode, there is retardation effect from the front sphere to the back sphere. The QNF from the front sphere is stronger than from the back sphere. In addition, due to the phase lag in k-direction, the QNF in transverse-X can differ quite significantly from transverse-Y for large particles. All these results could be understood when one considers how electric field from induced dipoles on neighboring NPs add on or subtract from the incident E-field. These results provide new insight into the coupling properties of Au NPs." @default.
- W3134712705 created "2021-03-15" @default.
- W3134712705 creator A5036120023 @default.
- W3134712705 creator A5061352985 @default.
- W3134712705 creator A5064752809 @default.
- W3134712705 creator A5071444345 @default.
- W3134712705 creator A5074411733 @default.
- W3134712705 date "2021-03-02" @default.
- W3134712705 modified "2023-10-03" @default.
- W3134712705 title "Insights on the Coupling of Plasmonic Nanoparticles from Near-Field Spectra Determined via Discrete Dipole Approximations" @default.
- W3134712705 cites W1963913631 @default.
- W3134712705 cites W1964564038 @default.
- W3134712705 cites W1968948784 @default.
- W3134712705 cites W1973714168 @default.
- W3134712705 cites W1975887566 @default.
- W3134712705 cites W1990815170 @default.
- W3134712705 cites W1994148821 @default.
- W3134712705 cites W1995929412 @default.
- W3134712705 cites W2000903543 @default.
- W3134712705 cites W2002848209 @default.
- W3134712705 cites W2007705442 @default.
- W3134712705 cites W2012605152 @default.
- W3134712705 cites W2014803909 @default.
- W3134712705 cites W2023822005 @default.
- W3134712705 cites W2025628651 @default.
- W3134712705 cites W2034758576 @default.
- W3134712705 cites W2048134161 @default.
- W3134712705 cites W2052395664 @default.
- W3134712705 cites W2054861547 @default.
- W3134712705 cites W2063877116 @default.
- W3134712705 cites W2068004998 @default.
- W3134712705 cites W2068909860 @default.
- W3134712705 cites W2078998802 @default.
- W3134712705 cites W2083926174 @default.
- W3134712705 cites W2085287693 @default.
- W3134712705 cites W2090262206 @default.
- W3134712705 cites W2105153592 @default.
- W3134712705 cites W2107154212 @default.
- W3134712705 cites W2122347920 @default.
- W3134712705 cites W2162246342 @default.
- W3134712705 cites W2301954252 @default.
- W3134712705 cites W2315578403 @default.
- W3134712705 cites W2316823983 @default.
- W3134712705 cites W2317692732 @default.
- W3134712705 cites W2461631668 @default.
- W3134712705 cites W2755294199 @default.
- W3134712705 cites W2794397745 @default.
- W3134712705 cites W2806523078 @default.
- W3134712705 cites W2915518183 @default.
- W3134712705 cites W2953724343 @default.
- W3134712705 cites W3008512465 @default.
- W3134712705 cites W9181081 @default.
- W3134712705 doi "https://doi.org/10.1021/acs.jpcc.1c01071" @default.
- W3134712705 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8341654" @default.
- W3134712705 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34367408" @default.
- W3134712705 hasPublicationYear "2021" @default.
- W3134712705 type Work @default.
- W3134712705 sameAs 3134712705 @default.
- W3134712705 citedByCount "5" @default.
- W3134712705 countsByYear W31347127052022 @default.
- W3134712705 crossrefType "journal-article" @default.
- W3134712705 hasAuthorship W3134712705A5036120023 @default.
- W3134712705 hasAuthorship W3134712705A5061352985 @default.
- W3134712705 hasAuthorship W3134712705A5064752809 @default.
- W3134712705 hasAuthorship W3134712705A5071444345 @default.
- W3134712705 hasAuthorship W3134712705A5074411733 @default.
- W3134712705 hasBestOaLocation W31347127052 @default.
- W3134712705 hasConcept C110879396 @default.
- W3134712705 hasConcept C121332964 @default.
- W3134712705 hasConcept C131584629 @default.
- W3134712705 hasConcept C155672457 @default.
- W3134712705 hasConcept C159467904 @default.
- W3134712705 hasConcept C171250308 @default.
- W3134712705 hasConcept C173523689 @default.
- W3134712705 hasConcept C191897082 @default.
- W3134712705 hasConcept C192562407 @default.
- W3134712705 hasConcept C202444582 @default.
- W3134712705 hasConcept C26873012 @default.
- W3134712705 hasConcept C30475298 @default.
- W3134712705 hasConcept C33923547 @default.
- W3134712705 hasConcept C41999313 @default.
- W3134712705 hasConcept C4839761 @default.
- W3134712705 hasConcept C49040817 @default.
- W3134712705 hasConcept C49874194 @default.
- W3134712705 hasConcept C62520636 @default.
- W3134712705 hasConcept C85255121 @default.
- W3134712705 hasConcept C9652623 @default.
- W3134712705 hasConceptScore W3134712705C110879396 @default.
- W3134712705 hasConceptScore W3134712705C121332964 @default.
- W3134712705 hasConceptScore W3134712705C131584629 @default.
- W3134712705 hasConceptScore W3134712705C155672457 @default.
- W3134712705 hasConceptScore W3134712705C159467904 @default.
- W3134712705 hasConceptScore W3134712705C171250308 @default.
- W3134712705 hasConceptScore W3134712705C173523689 @default.
- W3134712705 hasConceptScore W3134712705C191897082 @default.
- W3134712705 hasConceptScore W3134712705C192562407 @default.
- W3134712705 hasConceptScore W3134712705C202444582 @default.
- W3134712705 hasConceptScore W3134712705C26873012 @default.