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• W3134723003 abstract "To improve the dimensional thermal stability of polyethylene terephthalate (PET), a poly(ethylene glycol 1,4-cyclohexane dimethylene (CHDM) isosorbide (ISB) terephthalate) (PEICT) known as ECOZEN®T110 (EZT) was introduced into PET using a melt blending technique. The miscibility, morphology, and thermal properties of the PET/EZT samples were investigated. The introduction of amorphous EZT into semi-crystalline PET increased the glass transition temperature (Tg) but decreased the crystallinity, which could be related to the transesterification reaction. By adding EZT contents up to 20%, the PET/EZT samples showed a single Tg, which indicated the miscibility between PET and EZT. However, two Tg values were observed in the PET/EZT samples with higher EZT contents (30–70%), indicating partial miscibility. This may have been due to the slightly different rheological and thermodynamic parameters that were affected by a higher ratio of bulky (rigid ISB and ductile CHDM) groups in EZT. However, the heat distortion temperature of the PET/EZT samples remarkably increased, which indicated that the dimensional stability was truly enhanced. Although the crystallinity of the PET/EZT samples decreased with increasing EZT content, the tensile strength and Young’s modulus decreased slightly. Based on these results, the as-prepared PET/EZT samples with high dimensional stability can be used as a high-temperature polymeric material in various applications." @default.
• W3134723003 created "2021-03-15" @default.
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• W3134723003 date "2021-02-27" @default.
• W3134723003 modified "2023-10-17" @default.
• W3134723003 title "PET/Bio-Based Terpolyester Blends with High Dimensional Thermal Stability" @default.
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• W3134723003 doi "https://doi.org/10.3390/polym13050728" @default.
• W3134723003 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7956836" @default.
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