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- W3134793291 abstract "Temperature-programmed reduction of transition-metal phosphate precursors is the most commonly used method for the preparation of transition-metal phosphides (a new class of versatile metal catalysts), but the reduction processes are still not clear. Here we describe the construction of a temperature-programmed reduction-infrared spectroscopy apparatus (TPR-IR) to analyze the gas flows during the reduction of nickel, molybdenum, and tungsten phosphates. PH3 and Pn+ species already appeared in the gas flows at low temperature (ca. 200 °C), and PH3 was involved in the formation of phosphides. The emission of PH3 and Pn+ during the reduction of the molybdenum and tungsten phosphates was smaller than that of the nickel phosphate. Ni2P drastically accelerated the formation of the PH3 and Pn+. These results explain why excess phosphorus is needed for the preparation of Ni2P, and also demonstrate that the TPR-IR technique is an efficient method to understand the complex processes of catalyst preparation." @default.
- W3134793291 created "2021-03-15" @default.
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- W3134793291 date "2021-04-09" @default.
- W3134793291 modified "2023-10-18" @default.
- W3134793291 title "Understanding the Reduction of Transition‐Metal Phosphates to Transition‐Metal Phosphides by Combining Temperature‐Programmed Reduction and Infrared Spectroscopy" @default.
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- W3134793291 doi "https://doi.org/10.1002/anie.202100767" @default.
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