FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3135157419> ?p ?o ?g. }

• W3135157419 endingPage "10854" @default.
• W3135157419 startingPage "10845" @default.
• W3135157419 abstract "Cross-dehydrogenative coupling (CDC) is an effective tool for carbon–carbon bond formation in chemical synthesis. Herein, we report a metal–organic framework (MOF) possessing dual Lewis acidic Cr sites and sulfonic acid sites (MIL-101(Cr)–SO3H) as an efficient catalytic material for direct cross-coupling of xanthene and different nucleophiles using O2 as the oxidant. The highly porous structure of MIL-101(Cr)–SO3H enables the free access of reactants to the catalytic active sites inside MOF pores. Kinetic studies indicated that the Cr sites of MOF accelerate the rate-limiting autoxidation reaction of xanthene, which synergistically work with the sulfonic acid group on MOF ligands in promoting the CDC reactions. Besides, the catalytic system shows excellent functional group compatibility, and a variety of valuable xanthene derivatives were synthesized with satisfactory yields. Furthermore, MIL-101(Cr)–SO3H can be reused and its catalytic activity and crystal structure remain after six consecutive runs." @default.
• W3135157419 created "2021-03-15" @default.
• W3135157419 creator A5000195058 @default.
• W3135157419 creator A5001235693 @default.
• W3135157419 creator A5002188808 @default.
• W3135157419 creator A5035660881 @default.
• W3135157419 creator A5056236904 @default.
• W3135157419 creator A5081019345 @default.
• W3135157419 creator A5085934291 @default.
• W3135157419 creator A5091691715 @default.
• W3135157419 date "2021-03-02" @default.
• W3135157419 modified "2023-10-12" @default.
• W3135157419 title "Cooperative Interplay of Brønsted Acid and Lewis Acid Sites in MIL-101(Cr) for Cross-Dehydrogenative Coupling of C–H Bonds" @default.
• W3135157419 cites W1124032482 @default.
• W3135157419 cites W1963854859 @default.
• W3135157419 cites W1982558875 @default.
• W3135157419 cites W1984334231 @default.
• W3135157419 cites W1992861508 @default.
• W3135157419 cites W2002799357 @default.
• W3135157419 cites W2004550299 @default.
• W3135157419 cites W2007448187 @default.
• W3135157419 cites W2007661885 @default.
• W3135157419 cites W2011016996 @default.
• W3135157419 cites W2014818377 @default.
• W3135157419 cites W2018441875 @default.
• W3135157419 cites W2056570035 @default.
• W3135157419 cites W2068317562 @default.
• W3135157419 cites W2069640794 @default.
• W3135157419 cites W2073131911 @default.
• W3135157419 cites W2078490530 @default.
• W3135157419 cites W2081949897 @default.
• W3135157419 cites W2082373603 @default.
• W3135157419 cites W2083044780 @default.
• W3135157419 cites W2105761150 @default.
• W3135157419 cites W2110555379 @default.
• W3135157419 cites W2121122360 @default.
• W3135157419 cites W2121186265 @default.
• W3135157419 cites W2128434938 @default.
• W3135157419 cites W2149417324 @default.
• W3135157419 cites W2268018647 @default.
• W3135157419 cites W2294154527 @default.
• W3135157419 cites W2316480119 @default.
• W3135157419 cites W2327433125 @default.
• W3135157419 cites W2329076747 @default.
• W3135157419 cites W2528956049 @default.
• W3135157419 cites W2593828071 @default.
• W3135157419 cites W2672234276 @default.
• W3135157419 cites W2777651827 @default.
• W3135157419 cites W2792027474 @default.
• W3135157419 cites W2801165616 @default.
• W3135157419 cites W2886501096 @default.
• W3135157419 cites W2894014675 @default.
• W3135157419 cites W2946001619 @default.
• W3135157419 cites W2947386026 @default.
• W3135157419 cites W2947747894 @default.
• W3135157419 cites W2951142457 @default.
• W3135157419 cites W2955541462 @default.
• W3135157419 cites W2969825980 @default.
• W3135157419 cites W2977973524 @default.
• W3135157419 cites W2982500939 @default.
• W3135157419 cites W2986325536 @default.
• W3135157419 cites W2986497830 @default.
• W3135157419 cites W2994882025 @default.
• W3135157419 cites W3014055873 @default.
• W3135157419 cites W3020284887 @default.
• W3135157419 cites W3020400780 @default.
• W3135157419 cites W3020991290 @default.
• W3135157419 cites W3024584558 @default.
• W3135157419 cites W3033647377 @default.
• W3135157419 cites W3034733362 @default.
• W3135157419 cites W3036249518 @default.
• W3135157419 cites W3044722583 @default.
• W3135157419 cites W3045725363 @default.
• W3135157419 cites W3048146621 @default.
• W3135157419 cites W3048748416 @default.
• W3135157419 cites W3048904759 @default.
• W3135157419 cites W3082308478 @default.
• W3135157419 cites W3087025164 @default.
• W3135157419 cites W3088255640 @default.
• W3135157419 cites W3088709153 @default.
• W3135157419 cites W4234752353 @default.
• W3135157419 doi "https://doi.org/10.1021/acsami.0c20369" @default.
• W3135157419 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33648335" @default.
• W3135157419 hasPublicationYear "2021" @default.
• W3135157419 type Work @default.
• W3135157419 sameAs 3135157419 @default.
• W3135157419 citedByCount "11" @default.
• W3135157419 countsByYear W31351574192021 @default.
• W3135157419 countsByYear W31351574192022 @default.
• W3135157419 countsByYear W31351574192023 @default.
• W3135157419 crossrefType "journal-article" @default.
• W3135157419 hasAuthorship W3135157419A5000195058 @default.
• W3135157419 hasAuthorship W3135157419A5001235693 @default.
• W3135157419 hasAuthorship W3135157419A5002188808 @default.
• W3135157419 hasAuthorship W3135157419A5035660881 @default.
• W3135157419 hasAuthorship W3135157419A5056236904 @default.
• W3135157419 hasAuthorship W3135157419A5081019345 @default.
• W3135157419 hasAuthorship W3135157419A5085934291 @default.

• next