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• W3135263191 endingPage "094707" @default.
• W3135263191 startingPage "094707" @default.
• W3135263191 abstract "Precision engineering of defects in luminescent nanoscale crystalline materials with lesser controls to design is an area of interest in engineering materials with desired properties. Li+ co-doped BaYF5 nanocrystals were engineered, and temperature as controls for determining the co-dopant occupancies in the host lattice is studied. An observed enhancement in the up-conversion photoluminescence results from the co-dopant occupancy at Ba2+ sites via substitution through the hot injection method, whereas for samples prepared using co-precipitation, photoluminescence quenching was observed, which can be correlated with the Li+ occupancy at the interstitial site near Er3+ and also due to the incorporation of OH-. The crystal lattice deformation as a result of doping and the mechanism for the observed enhancement/quenching of luminescence are studied using x-ray diffraction, x-ray photoelectron spectroscopy, and energy transfer mechanism. Cytotoxicity assay and photoluminescence studies of the synthesized nanocrystals confirm that the material is biocompatible." @default.
• W3135263191 created "2021-03-15" @default.
• W3135263191 creator A5043029308 @default.
• W3135263191 creator A5070179482 @default.
• W3135263191 date "2021-03-07" @default.
• W3135263191 modified "2023-10-16" @default.
• W3135263191 title "Deciphering the role of temperature in Li⁺ co-dopant occupancy in BaYF₅:Yb³⁺,Er³⁺ up-converting nanocrystals and its structure–property relationship" @default.
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• W3135263191 doi "https://doi.org/10.1063/5.0033864" @default.
• W3135263191 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33685140" @default.
• W3135263191 hasPublicationYear "2021" @default.
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