FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3135352620> ?p ?o ?g. }

• W3135352620 endingPage "774" @default.
• W3135352620 startingPage "764" @default.
• W3135352620 abstract "The tetrabutylammonium salts of ionic organo-initiator containing N,N'-diisopropylthiourea (TUA-1) or N,N'-diethylthiourea (TUA-2) serve as inexpensive initiators for the anionic polymerization of methyl methacrylate (MMA) at room temperature. The molecular weights of obtained polymers are in the range of 1500–22,700 g mol−1 and the molecular weight distributions are fairly broad (Đ = 1.9–2.5) in optimized cases. The molar ratio of monomer to initiator can be achieved up to 800. Side-reactions, for example, backbiting, transfer reactions result in the polymerization being a non-living manner, thus leading to broad molecular weight distributions of the resulting polymers. The effects of counterion nature were also studied from the polymerization of MMA using TUA-1 anion with sodium or potassium salts as counterions under identical conditions. Detailed investigation indicates that the polymerization proceeds via a sulfur anion initiated repeated 1,4-Machael addition. In general, thioimidate initiators induced MMA polymerization feature certain induction periods, which is ascribed to slow addition thioimidate to CC double bond of MMA as a result of low initiator efficiency." @default.
• W3135352620 created "2021-03-15" @default.
• W3135352620 creator A5007958342 @default.
• W3135352620 creator A5010571980 @default.
• W3135352620 creator A5011972848 @default.
• W3135352620 date "2021-03-08" @default.
• W3135352620 modified "2023-10-16" @default.
• W3135352620 title "Synthetic and mechanistic aspects of anionic polymerization of methyl methacrylate using tetrabutyl ammonium thioimidate" @default.
• W3135352620 cites W1536051850 @default.
• W3135352620 cites W166851836 @default.
• W3135352620 cites W1900425694 @default.
• W3135352620 cites W1970886364 @default.
• W3135352620 cites W1972658742 @default.
• W3135352620 cites W1985002018 @default.
• W3135352620 cites W1986178312 @default.
• W3135352620 cites W1990773770 @default.
• W3135352620 cites W1993824338 @default.
• W3135352620 cites W1997914185 @default.
• W3135352620 cites W1999241195 @default.
• W3135352620 cites W1999880513 @default.
• W3135352620 cites W2000616337 @default.
• W3135352620 cites W2004234090 @default.
• W3135352620 cites W2005804621 @default.
• W3135352620 cites W2008626309 @default.
• W3135352620 cites W2009825820 @default.
• W3135352620 cites W2010650151 @default.
• W3135352620 cites W2021786716 @default.
• W3135352620 cites W2033743410 @default.
• W3135352620 cites W2034387102 @default.
• W3135352620 cites W2046106892 @default.
• W3135352620 cites W2048474098 @default.
• W3135352620 cites W2055137543 @default.
• W3135352620 cites W2061310847 @default.
• W3135352620 cites W2068894222 @default.
• W3135352620 cites W2080837087 @default.
• W3135352620 cites W2081324133 @default.
• W3135352620 cites W2084029873 @default.
• W3135352620 cites W2084151021 @default.
• W3135352620 cites W2086466871 @default.
• W3135352620 cites W2086615224 @default.
• W3135352620 cites W2087847610 @default.
• W3135352620 cites W2089760671 @default.
• W3135352620 cites W2095846627 @default.
• W3135352620 cites W2113057417 @default.
• W3135352620 cites W2132353954 @default.
• W3135352620 cites W2138736007 @default.
• W3135352620 cites W2145512912 @default.
• W3135352620 cites W2148481943 @default.
• W3135352620 cites W2149526001 @default.
• W3135352620 cites W2150072895 @default.
• W3135352620 cites W2313886708 @default.
• W3135352620 cites W2314796632 @default.
• W3135352620 cites W2417336535 @default.
• W3135352620 cites W2490175001 @default.
• W3135352620 cites W2577348619 @default.
• W3135352620 cites W2580264878 @default.
• W3135352620 cites W2747366464 @default.
• W3135352620 cites W2798151053 @default.
• W3135352620 cites W2897655684 @default.
• W3135352620 cites W2911190349 @default.
• W3135352620 cites W2986895162 @default.
• W3135352620 cites W3006826437 @default.
• W3135352620 cites W3043559162 @default.
• W3135352620 cites W3044657136 @default.
• W3135352620 cites W4211264019 @default.
• W3135352620 cites W4229743082 @default.
• W3135352620 cites W4246528915 @default.
• W3135352620 doi "https://doi.org/10.1002/pol.20200824" @default.
• W3135352620 hasPublicationYear "2021" @default.
• W3135352620 type Work @default.
• W3135352620 sameAs 3135352620 @default.
• W3135352620 citedByCount "1" @default.
• W3135352620 countsByYear W31353526202023 @default.
• W3135352620 crossrefType "journal-article" @default.
• W3135352620 hasAuthorship W3135352620A5007958342 @default.
• W3135352620 hasAuthorship W3135352620A5010571980 @default.
• W3135352620 hasAuthorship W3135352620A5011972848 @default.
• W3135352620 hasConcept C111998727 @default.
• W3135352620 hasConcept C145148216 @default.
• W3135352620 hasConcept C151286553 @default.
• W3135352620 hasConcept C158117686 @default.
• W3135352620 hasConcept C166940927 @default.
• W3135352620 hasConcept C178790620 @default.
• W3135352620 hasConcept C183882617 @default.
• W3135352620 hasConcept C185592680 @default.
• W3135352620 hasConcept C188027245 @default.
• W3135352620 hasConcept C2182769 @default.
• W3135352620 hasConcept C2777935641 @default.
• W3135352620 hasConcept C34814092 @default.
• W3135352620 hasConcept C44228677 @default.
• W3135352620 hasConcept C521977710 @default.
• W3135352620 hasConcept C79019126 @default.
• W3135352620 hasConcept C84687054 @default.
• W3135352620 hasConceptScore W3135352620C111998727 @default.
• W3135352620 hasConceptScore W3135352620C145148216 @default.
• W3135352620 hasConceptScore W3135352620C151286553 @default.
• W3135352620 hasConceptScore W3135352620C158117686 @default.
• W3135352620 hasConceptScore W3135352620C166940927 @default.

• next