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- W3135481010 endingPage "104789" @default.
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- W3135481010 abstract "TD-DFT quantum calculation was performed to predict and/or illustrate the electronic transition, the related absorption and emission maxima of some pyrrole-difluoroboron derivatives with different electron donor–acceptor unit or π-conjugated degree. Upon the calculated results, a new near infrared (NIR) fluorophore (abbreviated as TPBD-BP) was designed and fabricated through linking triphenylamine and pyrrole-difluoroboron units to benzothiadiazole (BTD) backbone. The fluorescence of TPBD-BP in solid state centered at 932 nm, which was 985 nm for TPBD-BP nanoparticles (TPBD-BP dots) encapsulated in PEG-6000. The fluorescence of TPBD-BP in both solid state and dots exhibited off-peak tail emission to NIR-II region (extended to 1300 nm). The TPBD-BP dots showed excellent water solubility, biocompatibility and aggregation induced emission (AIE), which was suitable to be applied in vivo imaging. NIR-II emission signal of TPBD-BP dots can be observed in the reproductive organ of normal nude mice after tail vein injection. This attractive combination of computational and experimental investigation would help to develop new-typed small-molecular NIR fluorophores." @default.
- W3135481010 created "2021-03-15" @default.
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- W3135481010 date "2021-05-01" @default.
- W3135481010 modified "2023-10-16" @default.
- W3135481010 title "A computational and experimental investigation of donor-acceptor BODIPY based near-infrared fluorophore for in vivo imaging" @default.
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- W3135481010 doi "https://doi.org/10.1016/j.bioorg.2021.104789" @default.
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