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- W3135491179 abstract "We report a mild palladium-catalyzed selective dehydrogenation of 4-alkylpyridines that exploits their soft enolization to alkylidene dihydropyridines using allyl chloroformate under metal-free conditions. Treatment of these intermediates with a palladium catalyst liberates an alkylpyridylic anion and an allylpalladium(II) intermediate, which combine and undergo β-hydride elimination to install a double bond. Importantly, the formation of gas byproducts makes the process very practical. Furthermore, the reaction tolerates a broad range of functional groups, including many that can be dehydrogenated using similar palladium-catalyzed reactions, and is selective for 4-alkylpyridines even in substrates bearing multiple pyridylic positions." @default.
- W3135491179 created "2021-03-15" @default.
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- W3135491179 date "2021-02-26" @default.
- W3135491179 modified "2023-10-16" @default.
- W3135491179 title "Palladium-Catalyzed, Mild Dehydrogenation of 4-Alkylpyridines" @default.
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- W3135491179 doi "https://doi.org/10.1021/acscatal.0c05209" @default.
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