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• W3135777617 abstract "Abstract A thermal process was employed to prepare a catalyst consisting of a mixture of metallic-Pt and rutile RuO 2 nanocrystals. This catalyst was used for the electrooxidation of 2-propanol in an alkaline solution. The effect of the catalyst composition on its microstructure, surface properties and catalytic activity was examined. With increasing the RuO 2 content, the catalytic activity increases, reaches its maximum and then decreases. The catalytic effect is a result of the bifunctional mechanism of the mixture of Pt and RuO 2 nanocrystals. The RuOH ad particles are formed on Ru atoms of the RuO 2 nanocrystals at potentials more negative than on Pt atoms. These oxy-species facilitate the dehydrogenation, breaking of C–C bonds and oxidation of both 2-propanol and its intermediates, adsorbed on assemblies of adjacent Pt atoms." @default.
• W3135777617 created "2021-03-15" @default.
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• W3135777617 date "2021-02-25" @default.
• W3135777617 modified "2023-10-01" @default.
• W3135777617 title "Electrooxidation of 2-propanol on the mixture of nanoparticles of Pt and RuO₂ supported on Ti" @default.
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• W3135777617 doi "https://doi.org/10.1515/zpch-2020-1794" @default.
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