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- W3136102540 abstract "This article describes the production of unsupported nickel phosphidecatalysts generated in situ in а reaction mixture from water-soluble andoil-soluble precursors during the hydroconversion of levulinic acid. Thesecatalysts contain crystalline phases, specificallyNi12P5 andNi(PO3)2. During thehydrogenation of levulinic acid in toluene in the presence of NiP–TOP, a lowertemperature and a shorter reaction time contribute to the formation ofγ-valerolactone (100% selectivity). A higher temperature and a longer reactiontime favor the formation of valeric acid (94% selectivity). In the hydrogenationof levulinic acid in ethanol in the presence ofNiP–H3PO2, the main reactionproduct is ethyl levulinate (95% selectivity)." @default.
- W3136102540 created "2021-03-29" @default.
- W3136102540 creator A5068513894 @default.
- W3136102540 date "2021-03-18" @default.
- W3136102540 modified "2023-10-14" @default.
- W3136102540 title "In Situ Generated Nickel Phosphide Based Catalysts for Hydroprocessing of Levulinic Acid" @default.
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- W3136102540 doi "https://doi.org/10.1134/s0965544121040022" @default.
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