Matches in SemOpenAlex for { <https://semopenalex.org/work/W3136150187> ?p ?o ?g. }
- W3136150187 endingPage "88" @default.
- W3136150187 startingPage "75" @default.
- W3136150187 abstract "Evolution of hydrogen from water by utilizing solar energy and photocatalysts is one of the most promising ways to solve energy crisis. However, designing a cost-effective and stable photocatalyst without any noble metals is of vital importance for this process. Herein, an extremely active molecular complex cocatalyst NiL2(Cl)2 is successfully designed. After being covalently linked to thiophene-embedded polymeric carbon nitride (TPCN), the hybrid catalyst NiL2(Cl)2/TPCN exhibits extraordinary H2 production activity of 95.8 μmol h−1 without Pt (λ ≥ 420 nm), together with a remarkable apparent quantum yield of 6.68% at 450 nm. In such a composite catalyst, the embedded π-electron-rich thiophene-ring not only extends the π-conjugated system to enhance visible light absorption, but also promotes the charge separation through electron-withdrawing effect. It turns out that the CN covalent bonds formed between NiL2(Cl)2 and TPCN skeleton accelerate the transfer of electrons to the Ni active sites. Our finding reveals that the strategy of embedding π-electron-rich compounds to graphitic carbon nitride provides potentials to develop excellent photocatalysts. The strong covalent combination of molecular complexes cocatalyst onto organic semiconductors represents an important step towards designing noble-metal-free photocatalysts with superior activity and high stability for visible light driven hydrogen evolution." @default.
- W3136150187 created "2021-03-29" @default.
- W3136150187 creator A5030406671 @default.
- W3136150187 creator A5062210887 @default.
- W3136150187 date "2021-08-01" @default.
- W3136150187 modified "2023-09-26" @default.
- W3136150187 title "Photocatalytic hydrogen evolution over a nickel complex anchoring to thiophene embedded g-C3N4" @default.
- W3136150187 cites W1990873132 @default.
- W3136150187 cites W1993943081 @default.
- W3136150187 cites W2008853118 @default.
- W3136150187 cites W2010953542 @default.
- W3136150187 cites W2028582051 @default.
- W3136150187 cites W2034492112 @default.
- W3136150187 cites W2058270577 @default.
- W3136150187 cites W2077822985 @default.
- W3136150187 cites W2085537246 @default.
- W3136150187 cites W2141704337 @default.
- W3136150187 cites W2142056348 @default.
- W3136150187 cites W2150399639 @default.
- W3136150187 cites W2159476098 @default.
- W3136150187 cites W2239593222 @default.
- W3136150187 cites W2314550610 @default.
- W3136150187 cites W2315353805 @default.
- W3136150187 cites W2330389407 @default.
- W3136150187 cites W2401906193 @default.
- W3136150187 cites W2470533104 @default.
- W3136150187 cites W2517716711 @default.
- W3136150187 cites W2569660464 @default.
- W3136150187 cites W2588349191 @default.
- W3136150187 cites W2588560876 @default.
- W3136150187 cites W2604885303 @default.
- W3136150187 cites W2607225757 @default.
- W3136150187 cites W2616992642 @default.
- W3136150187 cites W2741510344 @default.
- W3136150187 cites W2742530006 @default.
- W3136150187 cites W2752901269 @default.
- W3136150187 cites W2765238522 @default.
- W3136150187 cites W2788750592 @default.
- W3136150187 cites W2795076363 @default.
- W3136150187 cites W2796237602 @default.
- W3136150187 cites W2802412693 @default.
- W3136150187 cites W2804934748 @default.
- W3136150187 cites W2896430933 @default.
- W3136150187 cites W2902725153 @default.
- W3136150187 cites W2904555149 @default.
- W3136150187 cites W2909350829 @default.
- W3136150187 cites W2910091410 @default.
- W3136150187 cites W2910820311 @default.
- W3136150187 cites W2912966454 @default.
- W3136150187 cites W2914363040 @default.
- W3136150187 cites W2917798168 @default.
- W3136150187 cites W2936716119 @default.
- W3136150187 cites W2947501432 @default.
- W3136150187 cites W2961289620 @default.
- W3136150187 cites W2961611088 @default.
- W3136150187 cites W2970048356 @default.
- W3136150187 cites W2970292873 @default.
- W3136150187 cites W2970624419 @default.
- W3136150187 cites W2972939183 @default.
- W3136150187 cites W2973720187 @default.
- W3136150187 cites W2975785658 @default.
- W3136150187 cites W2979903023 @default.
- W3136150187 cites W2981624390 @default.
- W3136150187 cites W2994628508 @default.
- W3136150187 cites W2995217901 @default.
- W3136150187 cites W2995925157 @default.
- W3136150187 cites W2999089306 @default.
- W3136150187 cites W3005784197 @default.
- W3136150187 cites W3007085484 @default.
- W3136150187 cites W3010319871 @default.
- W3136150187 cites W3016916000 @default.
- W3136150187 cites W3024996301 @default.
- W3136150187 cites W3027981638 @default.
- W3136150187 cites W3035410057 @default.
- W3136150187 cites W3037682027 @default.
- W3136150187 cites W3080744450 @default.
- W3136150187 cites W3081829108 @default.
- W3136150187 cites W3082591985 @default.
- W3136150187 cites W3083122476 @default.
- W3136150187 cites W3084200785 @default.
- W3136150187 doi "https://doi.org/10.1016/j.jcis.2021.03.080" @default.
- W3136150187 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33838327" @default.
- W3136150187 hasPublicationYear "2021" @default.
- W3136150187 type Work @default.
- W3136150187 sameAs 3136150187 @default.
- W3136150187 citedByCount "26" @default.
- W3136150187 countsByYear W31361501872021 @default.
- W3136150187 countsByYear W31361501872022 @default.
- W3136150187 countsByYear W31361501872023 @default.
- W3136150187 crossrefType "journal-article" @default.
- W3136150187 hasAuthorship W3136150187A5030406671 @default.
- W3136150187 hasAuthorship W3136150187A5062210887 @default.
- W3136150187 hasConcept C104663316 @default.
- W3136150187 hasConcept C112613896 @default.
- W3136150187 hasConcept C127413603 @default.
- W3136150187 hasConcept C159985019 @default.
- W3136150187 hasConcept C161790260 @default.
- W3136150187 hasConcept C171250308 @default.