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- W3136198775 abstract "Recent advances in the desilylative acylation of 1-alkenylsilanes with acid anhydrides under transition metal catalysis are summarized. This catalytic desilylative acylation of 1-alkenylsilanes provides an efficient route to α,β-unsaturated ketones by using rhodium or iridium as the catalyst. Moreover, various one pot sequence reactions have been developed, which can synthesize α,β-unsaturated ketones from simple starting materials in an economic way. Additionally, this approach is applied to the asymmetric synthesis of atropisomers possessing silanol groups with excellent enantioselectivity." @default.
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- W3136198775 date "2021-09-01" @default.
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- W3136198775 title "Narasaka reaction: Desilylative acylation of 1-alkenylsilanes with acid anhydrides" @default.
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- W3136198775 doi "https://doi.org/10.1016/j.cclet.2021.03.033" @default.
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