Matches in SemOpenAlex for { <https://semopenalex.org/work/W3136199496> ?p ?o ?g. }
- W3136199496 endingPage "4632" @default.
- W3136199496 startingPage "4625" @default.
- W3136199496 abstract "The designing of tunable molecular systems that can host spin qubits is a promising strategy for advancing the development of quantum information science (QIS) applications. Photogenerated radical pairs are good spin qubit pair (SQP) candidates because they can be initialized in a pure quantum state that exhibits relatively long coherence times. DNA is a well-studied molecular system that allows for control of energetics and spatial specificity through careful design and thus serves as a tunable scaffold on which to control multispin interactions. Here, we examine a series of DNA hairpins that use naphthalenediimide (NDI) as the hairpin linker. Photoexcitation of the NDI leads to subnanosecond oxidation of guanine (G) within the duplex or a stilbenediether (Sd) end-cap to give NDI•–-G•+ or NDI•–-Sd•+ SQPs, respectively. A 2,2,6,6-tetramethylpiperdinyl-1-oxyl (TEMPO) stable radical is covalently attached to the hairpin at varying distances from the SQP spins. While TEMPO has a minimal effect on the SQP formation and decay dynamics, EPR spectroscopy indicates that there are significant spin–spin dipolar interactions between the SQP and TEMPO. We also demonstrate the ability to implement more complex spin manipulations of the NDI•–-Sd•+-TEMPO system using pulse-EPR techniques, which is important for developing DNA hairpins for QIS applications." @default.
- W3136199496 created "2021-03-29" @default.
- W3136199496 creator A5016795106 @default.
- W3136199496 creator A5024760717 @default.
- W3136199496 creator A5034903602 @default.
- W3136199496 creator A5049153440 @default.
- W3136199496 creator A5069446015 @default.
- W3136199496 creator A5072522213 @default.
- W3136199496 date "2021-03-18" @default.
- W3136199496 modified "2023-09-27" @default.
- W3136199496 title "Interaction of Photogenerated Spin Qubit Pairs with a Third Electron Spin in DNA Hairpins" @default.
- W3136199496 cites W1588340795 @default.
- W3136199496 cites W1964056885 @default.
- W3136199496 cites W1966332506 @default.
- W3136199496 cites W1984759551 @default.
- W3136199496 cites W1992381070 @default.
- W3136199496 cites W1993177615 @default.
- W3136199496 cites W1994827289 @default.
- W3136199496 cites W2000148947 @default.
- W3136199496 cites W2001348432 @default.
- W3136199496 cites W2012494234 @default.
- W3136199496 cites W2012840299 @default.
- W3136199496 cites W2030631573 @default.
- W3136199496 cites W2057392712 @default.
- W3136199496 cites W2063543183 @default.
- W3136199496 cites W2065777323 @default.
- W3136199496 cites W2065810679 @default.
- W3136199496 cites W2072435159 @default.
- W3136199496 cites W2073319590 @default.
- W3136199496 cites W2079085674 @default.
- W3136199496 cites W2081957610 @default.
- W3136199496 cites W2091201245 @default.
- W3136199496 cites W2094539896 @default.
- W3136199496 cites W2095211795 @default.
- W3136199496 cites W2132764286 @default.
- W3136199496 cites W2145022509 @default.
- W3136199496 cites W2158605123 @default.
- W3136199496 cites W2314472587 @default.
- W3136199496 cites W2319222017 @default.
- W3136199496 cites W2319574108 @default.
- W3136199496 cites W2321752750 @default.
- W3136199496 cites W2322485605 @default.
- W3136199496 cites W2324811969 @default.
- W3136199496 cites W2327342770 @default.
- W3136199496 cites W2336272707 @default.
- W3136199496 cites W2340955618 @default.
- W3136199496 cites W2518363479 @default.
- W3136199496 cites W2557571154 @default.
- W3136199496 cites W2563806409 @default.
- W3136199496 cites W2592524846 @default.
- W3136199496 cites W2618538725 @default.
- W3136199496 cites W2740119922 @default.
- W3136199496 cites W2754797405 @default.
- W3136199496 cites W2765801447 @default.
- W3136199496 cites W2789212465 @default.
- W3136199496 cites W2887585517 @default.
- W3136199496 cites W289094471 @default.
- W3136199496 cites W2901785342 @default.
- W3136199496 cites W2908724756 @default.
- W3136199496 cites W2910915889 @default.
- W3136199496 cites W2960186007 @default.
- W3136199496 cites W2976938114 @default.
- W3136199496 cites W2996413636 @default.
- W3136199496 cites W2998281648 @default.
- W3136199496 cites W3004335076 @default.
- W3136199496 cites W3104946176 @default.
- W3136199496 cites W4254297188 @default.
- W3136199496 doi "https://doi.org/10.1021/jacs.0c12645" @default.
- W3136199496 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33735563" @default.
- W3136199496 hasPublicationYear "2021" @default.
- W3136199496 type Work @default.
- W3136199496 sameAs 3136199496 @default.
- W3136199496 citedByCount "10" @default.
- W3136199496 countsByYear W31361994962021 @default.
- W3136199496 countsByYear W31361994962022 @default.
- W3136199496 countsByYear W31361994962023 @default.
- W3136199496 crossrefType "journal-article" @default.
- W3136199496 hasAuthorship W3136199496A5016795106 @default.
- W3136199496 hasAuthorship W3136199496A5024760717 @default.
- W3136199496 hasAuthorship W3136199496A5034903602 @default.
- W3136199496 hasAuthorship W3136199496A5049153440 @default.
- W3136199496 hasAuthorship W3136199496A5069446015 @default.
- W3136199496 hasAuthorship W3136199496A5072522213 @default.
- W3136199496 hasConcept C121332964 @default.
- W3136199496 hasConcept C155220765 @default.
- W3136199496 hasConcept C159467904 @default.
- W3136199496 hasConcept C177462420 @default.
- W3136199496 hasConcept C181500209 @default.
- W3136199496 hasConcept C184779094 @default.
- W3136199496 hasConcept C185592680 @default.
- W3136199496 hasConcept C187961010 @default.
- W3136199496 hasConcept C203087015 @default.
- W3136199496 hasConcept C26873012 @default.
- W3136199496 hasConcept C2778870898 @default.
- W3136199496 hasConcept C42704618 @default.
- W3136199496 hasConcept C46141821 @default.
- W3136199496 hasConcept C62520636 @default.
- W3136199496 hasConcept C84114770 @default.