Matches in SemOpenAlex for { <https://semopenalex.org/work/W3136203019> ?p ?o ?g. }
- W3136203019 endingPage "116603" @default.
- W3136203019 startingPage "116603" @default.
- W3136203019 abstract "The influence of different metal oxides (ZnO, ZrO2, In2O3) in CO2 hydrogenation to methanol over Cu-based catalysts was studied. The catalysts were characterized using x-ray diffraction (XRD), thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), N2-physisorption, N2O chemisorption, H2 temperature-programmed reduction (H2-TPR), and CO2 temperature-programmed desorption (CO2-TPD). It was found that impregnating ZrO2 onto Cu/ZnO enhances the methanol formation rate from 14.7 mmol∙gcat−1∙h−1 to 15.6 mmol∙gcat−1∙h−1 (230 °C, 30 bar, 38 000 cm3/(gcat h)), which is attributed to the formation of Cu-ZrO2 sites. The results also indicate that In-doping of the Cu-based catalysts generates CuxIny alloys, which seems to inhibit the active sites on the Cu surface. However, new sites for methanol synthesis are present when Cu/ZrO2/In2O3 is prepared by co-precipitation. This is attributed to In-Zr mixed oxide species that increases the methanol formation rate from 53.2 mmol∙gcat−1∙h−1 to 60.5 mmol∙gcat−1∙h−1 (270 °C, 30 bar, 140 000 cm3/(gcat h))." @default.
- W3136203019 created "2021-03-29" @default.
- W3136203019 creator A5004580655 @default.
- W3136203019 creator A5019141403 @default.
- W3136203019 creator A5036194139 @default.
- W3136203019 creator A5080392396 @default.
- W3136203019 creator A5091072607 @default.
- W3136203019 date "2021-07-01" @default.
- W3136203019 modified "2023-09-30" @default.
- W3136203019 title "Tuning the interfacial sites between copper and metal oxides (Zn, Zr, In) for CO2 hydrogenation to methanol" @default.
- W3136203019 cites W1495226571 @default.
- W3136203019 cites W1537155220 @default.
- W3136203019 cites W1571427581 @default.
- W3136203019 cites W157435212 @default.
- W3136203019 cites W1583451004 @default.
- W3136203019 cites W163127321 @default.
- W3136203019 cites W1965663951 @default.
- W3136203019 cites W1969790108 @default.
- W3136203019 cites W1991692033 @default.
- W3136203019 cites W1997876805 @default.
- W3136203019 cites W2011377242 @default.
- W3136203019 cites W2016692492 @default.
- W3136203019 cites W2021305023 @default.
- W3136203019 cites W2022258254 @default.
- W3136203019 cites W2022425777 @default.
- W3136203019 cites W2026082383 @default.
- W3136203019 cites W2028009023 @default.
- W3136203019 cites W2032154528 @default.
- W3136203019 cites W2038270472 @default.
- W3136203019 cites W2040442625 @default.
- W3136203019 cites W2045885909 @default.
- W3136203019 cites W2047482670 @default.
- W3136203019 cites W2060710374 @default.
- W3136203019 cites W2061342865 @default.
- W3136203019 cites W2063198976 @default.
- W3136203019 cites W2129837023 @default.
- W3136203019 cites W2145662064 @default.
- W3136203019 cites W2149941988 @default.
- W3136203019 cites W2154032029 @default.
- W3136203019 cites W2210344242 @default.
- W3136203019 cites W2265853247 @default.
- W3136203019 cites W2280487064 @default.
- W3136203019 cites W2283009411 @default.
- W3136203019 cites W2293504145 @default.
- W3136203019 cites W2300085411 @default.
- W3136203019 cites W2317607900 @default.
- W3136203019 cites W2326809340 @default.
- W3136203019 cites W2345476069 @default.
- W3136203019 cites W2438343038 @default.
- W3136203019 cites W2511433364 @default.
- W3136203019 cites W2521192923 @default.
- W3136203019 cites W2528194497 @default.
- W3136203019 cites W2547779722 @default.
- W3136203019 cites W2579891120 @default.
- W3136203019 cites W2600566292 @default.
- W3136203019 cites W266668937 @default.
- W3136203019 cites W2788637447 @default.
- W3136203019 cites W2789831154 @default.
- W3136203019 cites W2790977363 @default.
- W3136203019 cites W2792497350 @default.
- W3136203019 cites W2883390734 @default.
- W3136203019 cites W2884737359 @default.
- W3136203019 cites W2909269137 @default.
- W3136203019 cites W2916865785 @default.
- W3136203019 cites W2920485654 @default.
- W3136203019 cites W2928124942 @default.
- W3136203019 cites W2943094369 @default.
- W3136203019 cites W2953427046 @default.
- W3136203019 cites W2955213442 @default.
- W3136203019 cites W2962783981 @default.
- W3136203019 cites W2966615249 @default.
- W3136203019 cites W2979291573 @default.
- W3136203019 cites W2996686065 @default.
- W3136203019 cites W3001149871 @default.
- W3136203019 cites W3010621086 @default.
- W3136203019 cites W3024049792 @default.
- W3136203019 cites W3034051096 @default.
- W3136203019 cites W3085524505 @default.
- W3136203019 cites W3100529310 @default.
- W3136203019 cites W4240394083 @default.
- W3136203019 doi "https://doi.org/10.1016/j.ces.2021.116603" @default.
- W3136203019 hasPublicationYear "2021" @default.
- W3136203019 type Work @default.
- W3136203019 sameAs 3136203019 @default.
- W3136203019 citedByCount "22" @default.
- W3136203019 countsByYear W31362030192021 @default.
- W3136203019 countsByYear W31362030192022 @default.
- W3136203019 countsByYear W31362030192023 @default.
- W3136203019 crossrefType "journal-article" @default.
- W3136203019 hasAuthorship W3136203019A5004580655 @default.
- W3136203019 hasAuthorship W3136203019A5019141403 @default.
- W3136203019 hasAuthorship W3136203019A5036194139 @default.
- W3136203019 hasAuthorship W3136203019A5080392396 @default.
- W3136203019 hasAuthorship W3136203019A5091072607 @default.
- W3136203019 hasBestOaLocation W31362030191 @default.
- W3136203019 hasConcept C13965031 @default.
- W3136203019 hasConcept C147789679 @default.
- W3136203019 hasConcept C150394285 @default.