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• W3136222600 abstract "Improving interfacial interactions by constructing heterostructures is gaining interest due to its unique structural benefits for ion-reservoir applications. However, great challenges remain. Herein, we propose MoS2 nanorod-based heterostructures covered with a closely interconnected Sn and Mo sulfides/carbon matrix ([email protected]) (engraved by a simple water based surface exfoliation strategy) as an efficient anode material for Li/Na–ion storage. Our hierarchical [email protected] electrode achieved remarkable discharge capacities of 1,060 and 490 mAh g−1 (after 100 cycles at 100 mA g−1) for lithium and sodium-ion batteries, respectively, along with high initial coulombic efficiency and rate capability. This well-constructed architecture provided facile Li+/Na+ ion diffusion and enhanced the charge transfer at the heterointerfaces. Meanwhile, the strong coupling of MoS2 with SnS during water exfoliation in the presence of a carbon matrix created a stable and shielded nanostructure, which significantly enhanced electron/ion transport and mitigated the volume expansion during cycling. These benefits were attributed to a prominent capacitive contribution from kinetics study, improved Li+/Na+ diffusion from galvanostatic intermittent titration measurements, and good structural stability from ex-situ analyses." @default.
• W3136222600 created "2021-03-29" @default.
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• W3136222600 date "2021-06-01" @default.
• W3136222600 modified "2023-10-03" @default.
• W3136222600 title "Closely Coupled Binary Metal Sulfide Nanosheets Shielded Molybdenum Sulfide Nanorod Hierarchical Structure via Eco-Benign Surface Exfoliation Strategy towards Efficient Lithium and Sodium-ion Batteries" @default.
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• W3136222600 doi "https://doi.org/10.1016/j.ensm.2021.03.022" @default.
• W3136222600 hasPublicationYear "2021" @default.
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