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- W3136227888 endingPage "2049" @default.
- W3136227888 startingPage "2042" @default.
- W3136227888 abstract "Abstract Although both stable free organic radicals and biomass‐derived hydrochars have emerged as appealing, green, multifunctional materials, their association has not been explored. In this study, strength is found to lie in their union, which primarily leads to stable redox‐active free‐radical‐hydrochar composites that can generate unexpected opportunities for the development of advanced metal‐free sustainable materials. The composites are obtained by a straightforward green one‐pot hydrothermal procedure. The loading of stable free radicals of nitroxide type and their localization is engineered by the nature of the carbohydrate and the reaction status; vigorous reaction parameters promote faster nucleation and growth kinetics of the hydrochar products, leading to a covalent immobilization of redox species on the surface of the carbonaceous microspherical aggregates. The nitroxide free‐radical‐hydrochar materials demonstrate enhancements in terms of both electrocatalytic activity and capacitive features." @default.
- W3136227888 created "2021-03-29" @default.
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- W3136227888 date "2021-03-31" @default.
- W3136227888 modified "2023-10-18" @default.
- W3136227888 title "Rational Functionalization Towards Redox‐Active TEMPO Stable Free‐Radical‐Hydrochar Composites" @default.
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- W3136227888 doi "https://doi.org/10.1002/cssc.202100100" @default.
- W3136227888 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33734591" @default.
- W3136227888 hasPublicationYear "2021" @default.
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