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- W3136258986 abstract "Unique properties of graphene open new opportunities for preparing composites with favorable functional capabilities. Herein, an ingenious synthesis route via re-pyrolysis process of ball-milling-induced SiC(rGO, G x ) p fillers/polycarbosilane-vinyltriethoxysilane-graphene oxide (PCS-VTES-GO, PVG) precursors blends is proposed to obtain structural-functional integrated SiC(rGO, G x ) bulk polymer-derived ceramics (PDCs). The introduction of SiC(rGO, G x ) p provides favorable moldability, ceramic yield and linear shrinkage. Attractively, graphene networks with more free-moving electrical-charge carriers and wider phonon-channel prominently enhance electrical and thermal conductivities of products. Particularly, SiC(rGO, G 20% ) bulk PDCs generated at 1300 °C own satisfactory ceramic yield (90.74%), linear shrinkage (5.00%), fracture toughness (2.07 MPa m 1/2 ), bending strength (35.37 MPa), electrical conductivity (25.72 S cm −1 ) and thermal conductivity (6.72 W m −1 ·K −1 ), realizing outstanding values to the best of our knowledge. This fabrication method favors mass production of larger-sized PDCs and possess potential emerging uses. • Structural-functional integrated SiC(rGO, G x ) bulk PDCs were ingeniously built. • Graphene networks combine unique structural-functional characteristics for bulk PDCs. • Ceramic yield reaches 90.74% while liner shrinkage efficiently decreases to 5.00%. • Electrical and thermal conductivities rapidly attain 25.72 S cm −1 and 6.72 W m −1 ·K −1 . • Mass production of large-sized PDCs for aerospace components is expected to achieve." @default.
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- W3136258986 date "2021-07-01" @default.
- W3136258986 modified "2023-10-14" @default.
- W3136258986 title "Using graphene networks to build SiC(rGO, Gx) bulk ceramics from polymeric precursors" @default.
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- W3136258986 doi "https://doi.org/10.1016/j.ceramint.2021.03.170" @default.
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