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• W3136263157 endingPage "2789" @default.
• W3136263157 startingPage "2783" @default.
• W3136263157 abstract "Singlet nucleophilic carbenes (SNCs) containing only one heteroatom donor remain underutilized in chemical synthesis. We recently discovered that visible-light-induced SNC intermediates can be trapped by fluorinated ketones via 1,2-carbonyl addition to afford benzoin-type products. This discovery represents a rare example of nucleophilic carbenes reacting with ketones and delivers an efficient, user-friendly, and scalable process for accessing fluorinated tertiary alcohol derivatives driven only by light circumventing the use of exogenous catalysts or additives." @default.
• W3136263157 created "2021-03-29" @default.
• W3136263157 creator A5037159175 @default.
• W3136263157 creator A5042130432 @default.
• W3136263157 creator A5071375075 @default.
• W3136263157 creator A5077451285 @default.
• W3136263157 date "2021-03-18" @default.
• W3136263157 modified "2023-10-01" @default.
• W3136263157 title "Fluorinated Ketones as Trapping Reagents for Visible-Light-Induced Singlet Nucleophilic Carbenes" @default.
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