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- W3136267472 abstract "Optical fluorescence microscopy is shown to enable both high spatial and temporal resolution of redox-dependent fluorescence in flowing electrolytes. We report the use of fluorescence microscopy coupled with electrochemistry to directly observe the reaction and transport of redox-active quinones within porous carbon electrodes in operando. We observe surprising electrolyte channeling features within several porous electrodes, leading to spatially distinguishable advection-dominated and diffusion-dominated regions. These results challenge the common assumption that transport in porous electrodes can be approximated by a homogeneous Darcy-like permeability, particularly at the length scales relevant to many electrochemical systems such as redox flow batteries. This work presents a new platform to provide highly resolved spatial and temporal insight into electrolyte reactions and transport behavior within porous electrodes." @default.
- W3136267472 created "2021-03-29" @default.
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- W3136267472 date "2021-04-01" @default.
- W3136267472 modified "2023-10-18" @default.
- W3136267472 title "Direct visualization of electrochemical reactions and heterogeneous transport within porous electrodes in operando by fluorescence microscopy" @default.
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- W3136267472 doi "https://doi.org/10.1016/j.xcrp.2021.100388" @default.
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