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- W3136269938 abstract "Ce-based intermetallics are of interest due to the potential to study the interplay of localized magnetic moments and conduction electrons. Our work on Ce-based germanides led to the identification of a new homologous series An+1MnX3n+1 (A = rare earth, M = transition metal, X = tetrels, and n = 1–6). This work presents the single-crystal growth, structure determination, and anisotropic magnetic properties of the n = 4 member of the Cen+1ConGe3n+1 homologous series. Ce5Co4+xGe13−ySny consists of three Ce sites, three Co sites, seven Ge sites, and two Sn sites, and the crystal structure is best modeled in the orthorhombic space group Cmmm where a = 4.3031(8) Å, b = 45.608(13) Å, and c = 4.3264(8) Å, which is in close agreement with the previously reported Sn-free analog where a = 4.265(1) Å, b = 45.175(9) Å, and c = 4.293(3) Å. Anisotropic magnetic measurements show Kondo-like behavior and three magnetic transitions at 6, 4.9, and 2.4 K for Ce5Co4+xGe13−ySny." @default.
- W3136269938 created "2021-03-29" @default.
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- W3136269938 date "2021-03-16" @default.
- W3136269938 modified "2023-10-14" @default.
- W3136269938 title "Fantastic <i>n</i> = 4: Ce<sub>5</sub>Co<sub>4+x</sub>Ge<sub>13−y</sub>Sn<sub>y</sub> of the A<sub><i>n</i>+1</sub>M<sub><i>n</i></sub>X<sub>3<i>n</i>+1</sub> homologous series" @default.
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- W3136269938 doi "https://doi.org/10.1063/5.0045015" @default.
- W3136269938 hasPublicationYear "2021" @default.
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