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• W3136272012 endingPage "109325" @default.
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• W3136272012 abstract "This study performs a sono-photochemical method to get more effective therapeutic outcomes for cancer treatment. Additionally, sonochemical and sono-photochemical properties of lutetium phthalocyanines have been presented in this study for the first time. Although it aims to synthesize a series of new peripherally/non-peripherally mono lutetium (III) phthalocyanines ( 1-3Lu ), the related double-decker lutetium (III) phthalocyanines ( 1′-3′Lu ) were simultaneously synthesized. Characterization of the resulting macromolecules was carried out using diverse spectroscopic approaches including NMR ( 1 H and 13 C NMR; for 1-3Lu ), UV–Vis, FT-IR, and Mass spectroscopy. The double-decker lutetium (III) phthalocyanines ( 1′-3′Lu ) were also characterized by performing electron spin resonance (ESR) measurements. The solubility of all the new macromolecules was studied using different polar and non-polar organic solvents. The photophysicochemical properties of the resulting mono lutetium (III) complexes were analyzed and photochemical, sonochemical, and sono-photochemical properties were investigated to determine the efficiencies of singlet oxygen. When the data were compared, the highest singlet oxygen quantum yields (Φ Δ = 0.86 for 1-Lu , 0.96 for 2-Lu , 0.83 for 3-Lu ) were obtained for the sono-photochemical studies. The results prove that sono-photochemical properties improve the therapeutic effects compared to photochemical ones. • Peripherally/non-peripherally tetra-substituted mono/double-decker lutetium compounds bearing fluorine atoms were prepared. • Peripherally octa-substituted mono/double-decker lutetium phthalocyanines containing fluorine atoms were prepared. • The photophysico-chemical properties of the mono lutetium (III) complexes were analyzed. • For the first, time photochemical and sono-photochemical properties of the mono lutetium (III) complexes were investigated. • The efficiency of singlet oxygen was calculated using two methods and was compared." @default.
• W3136272012 created "2021-03-29" @default.
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• W3136272012 date "2021-06-01" @default.
• W3136272012 modified "2023-10-01" @default.
• W3136272012 title "Comparatively singlet oxygen efficiency by sono-photochemical and photochemical studies of new lutetium (III) phthalocyanines" @default.
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• W3136272012 doi "https://doi.org/10.1016/j.dyepig.2021.109325" @default.
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